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Fuel Cell Employing Hydrated Non-Perfluorinated Hydrocarbon Ion Exchange Membrane

机译:采用水合非全氟化烃离子交换膜的燃料电池

摘要

Fuel cells (9) include unitized electrode assemblies (12) having a non-perfluorinated hydrocarbon ionomer exchange membrane (26) with anode and cathode catalysts (27, 28) disposed on opposite sides thereof. Adjacent the catalysts, respective optional sublayers (29, 30) may be supported by corresponding gas diffusion layers (31, 32), with adjacent porous, hydrophilic, water transferring reactant gas flow field plates (13, 14) having respective fuel (17) and oxidant (23) reactant gas flow field channels. Water channels (18, 19, 20)hydrate the membrane (26), clear the product water from the cathode (28, 30, 32), flush peroxide radicals, and may also cool the fuel cells. Improved performance (124) (higher voltage at higher current densities) is achieved along with elimination of a propensity for degradation from peroxide decomposition products resulting from oxygen solubility of perfluorinated membranes. Platinum/ruthenium alloy anode catalysts improve performance without degradation which occurs with perfluorinated membranes.
机译:燃料电池( 9 )包括带有非全氟化烃离聚物交换膜( 26 )和阳极和阴极催化剂的单元电极组件( 12 ) ( 27,28 )置于其相对两侧。邻近催化剂,各个可选的子层( 29、30 )可以由相应的气体扩散层( 31,32 )支撑,并带有相邻的多孔,亲水性,水转移反应气体流场板( 13、14 )具有相应的燃料( 17 )和氧化剂( 23 )反应气体流场通道。水通道( 18、19、20 )使膜( 26 )水合,从阴极清除产品水( 28、30、32 ),冲洗过氧化物自由基,并且还可能使燃料电池冷却。改善了性能( 124 )(在较高的电流密度下具有更高的电压),并且消除了由于全氟化膜的氧溶解度而导致的过氧化物分解产物降解的可能性。铂/钌合金阳极催化剂可提高性能,而不会发生全氟化膜发生降解的情况。

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