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METHOD FOR THE WET-CHEMICAL ETCHING OF TIO2 THIN-FILMS AND TIO2 PARTICLES AND ETCHING REAGENT

机译:TIO2薄膜和TIO2颗粒的湿化学蚀刻方法及蚀刻试剂

摘要

The invention relates to a method and an etching reagent for the wet-chemical etching of TiO2 thin-films and TiO2particles that permits a defined removal of the TiO2thin-film and a reduction of the particle size. The method comprises the steps: production of an etching reagent with a pH value greater than 13, said reagent containing a base with a concentration of 0.1 mol, selected from the bases NH4OH, NaOH, KOH or mixtures of the same and H2O2 with a smaller concentration than that of the base; setting of a temperature that is equal to or greater than the ambient temperature; immersion of the TiO2 thin-films and TiO2 particles in the etching reagent and steeping of the layers of the TiO2 thin-films and particles; said films and particles are then rinsed with distilled water and dried. To maintain the initial composition of the etching reagent, H2O2 is added during the etching process.
机译:本发明涉及用于湿化学蚀刻TiO 2薄膜和TiO 2颗粒的方法和蚀刻剂,其允许明确地去除TiO 2薄膜和减小粒径。所述方法包括以下步骤:生产pH值大于13的蚀刻剂,所述试剂包含浓度为> 0.1mol的碱,所述碱选自NH 4 OH,NaOH,KOH或它们的混合物和H 2 O 2与H 2 O 2的混合物。浓度小于碱浓度;设定等于或高于环境温度的温度;将TiO 2薄膜和TiO 2颗粒浸入蚀刻剂中,并使TiO 2薄膜和颗粒的层变陡;然后将所述膜和颗粒用蒸馏水冲洗并干燥。为了保持蚀刻剂的初始组成,在蚀刻过程中要加入H2O2。

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