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High-level and high-stability dehydrogenation catalysts based on iron oxides with a low concentration of titanium and its formulation and use of

机译:基于低钛铁氧化物的高水平高稳定性脱氢催化剂及其制备和用途

摘要

1. The composition of the dehydrogenation catalyst based on iron oxide, comprising: an iron oxide component having a low titanium content, wherein said iron oxide component is obtained by heat treatment of a yellow iron oxide precipitate prepared from an iron salt solution by precipitation, and wherein said dehydrogenation catalyst composition based oxide iron has a first concentration of titanium that is less than about 300 hours. / mln.2. A composition according to claim 1, wherein said yellow iron oxide precipitate has a second concentration of titanium that is less than about 300 ppm / mln.3. A composition according to claim 2, wherein said yellow iron oxide precipitate further is characterized in that it is formed by adding a colloidal hydrate of iron to an aqueous solution of an iron salt, wherein said aqueous solution contains metallic iron, by introducing an oxidant into said aqueous solution and by precipitation and isolating said precipitate of yellow zheleza.4 oxide. A composition according to claim 3, wherein said dehydrogenation catalyst composition based on the iron oxide further includes an additional dehydrogenation catalyst component selected from the group of compounds consisting of potassium compounds, cerium compounds, molybdenum compounds, tungsten compounds and kaltsiya.5 compounds. A composition according to claim 4, wherein said dehydrogenation catalyst composition based on the iron oxide further comprises iron oxide in an amount of from 10 to 98% of the total weight of the composition of the dehydrogenation catalyst based on iron oxide and calculated for FeO.6. A composition according to claim 5, wherein said heat treatment is carried out
机译:1.基于氧化铁的脱氢催化剂的组合物,其包含:具有低钛含量的氧化铁组分,其中所述氧化铁组分通过热处理由铁盐溶液通过沉淀制备的黄色氧化铁沉淀而获得,并且其中所述基于脱氢催化剂组合物的氧化铁具有小于约300小时的钛的第一浓度。 / mln.2。 2.根据权利要求1的组合物,其中所述黄色氧化铁沉淀物的第二钛浓度小于约300ppm / ml.3。 3.根据权利要求2所述的组合物,其中,所述黄色氧化铁沉淀物的特征还在于,通过向铁盐的水溶液中添加铁的胶体水合物至铁盐的水溶液中而形成,所述铁盐的水溶液包含金属铁。所述水溶液,并通过沉淀和分离出所述黄色zheleza.4氧化物的沉淀。 4.根据权利要求3所述的组合物,其中,所述基于氧化铁的脱氢催化剂组合物还包含选自由钾化合物,铈化合物,钼化合物,钨化合物和kaltsiya.5化合物组成的组的另外的脱氢催化剂组分。 5.根据权利要求4的组合物,其中所述基于氧化铁的脱氢催化剂组合物进一步包含氧化铁,其含量为基于氧化铁的脱氢催化剂的组合物总重量的10-98%。 6。 6.根据权利要求5的组合物,其中所述热处理进行

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