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A Study of the Catalysts for the Complete Oxidation of Low Concentration Ethyl Acetate and n-Butyl Acetate

机译:低浓度乙酸乙酯和乙酸正丁酯完全氧化的催化剂的研究

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In this work, we have synthesized mixed oxides catalysts supported on γ-Al2O3,using some base metals such as La、 Sr、 Ce、 Ni、 Cu. At the space velocity of 56,000h-1 and at some range of concentration, the complete conversion temperatures( ≥ 98% )of Ethyl acetate and n-butyl acetate are 260℃ and 250℃ respectively. The work has an excellent prospect of industrial application.  I will introduce the experiment and results from the following tluee aspects. According to Figure 1, X-ray diffraction pattern of the catalyst have shown not only perovskite structure but also much independent CeO2 phase. During the preparation, the CeO2 was coated over support γ-A12O3 for the better Oxygen storage capacity .By co1mparison, we found that the activity of the catalyst with CeO2 was higher than the activity of the catalyst without CeO2.……
机译:在这项工作中,我们使用诸如La,Sr,Ce,Ni,Cu等贱金属合成了负载在γ-Al2O3上的混合氧化物催化剂。在56,000h-1的空速和一定的浓度范围内,乙酸乙酯和乙酸正丁酯的完全转化温度(≥98%)分别为260℃和250℃。这项工作在工业上有很好的应用前景。我将从以下胶水方面介绍实验和结果。根据图1,催化剂的X射线衍射图不仅显示出钙钛矿结构,而且还显示出非常独立的CeO2相。在制备过程中,将CeO2涂覆在载体γ-Al2O3上以具有更好的储氧能力。通过比较,我们发现含CeO2的催化剂的活性高于不含CeO2的催化剂的活性。……

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