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METHOD OF OBTAINING ADAPTABLE SORBENTS BASED ON POLYMERS WITH MOLECULAR IMPRINTS

机译:基于分子印迹聚合物的适应性吸附剂的获得方法

摘要

FIELD: chemistry.;SUBSTANCE: present invention relates to protection from poisonous substances. Proposed is a method of obtaining sorbents, adaptable to poisonous substances, hazardous chemical substances, highly toxic substances, and other toxic chemicals, including 2,2-dichloroethylsulphide (mustard gas), acid fluoride of isopropyl ether of methyl-phosphonic acid (sarin) and O-ethyl S-2-(N,N-diisopropylamine)ethyl ether of methyl-phosphonic acid (VX), based on polymers with molecular imprints using non-toxic or low-toxic structural analogues of toxic chemicals as template compounds, particularly: bis-2-chloroethyl ether (mustard gas analogue), O-methyl O-isoproplyl ether of methyl-phosphonic acid (sarin analogue) and O-ethyl O-2-(N,N-diisopropylamine) ethyl ether of methyl-phosphonic acid (VX analogue).;EFFECT: obtained sorbents have high sorption selectivity relative chosen toxic chemicals.;4 cl, 3 tbl, 3 ex,1 dwg
机译:技术领域本发明涉及防止有毒物质的方法。提出了一种适用于有毒物质,有害化学物质,剧毒物质和其他有毒化学物质的吸附剂的获取方法,包括2,2-二氯乙基硫化物(芥子气),甲基膦酸异丙基醚的酸性氟化物(沙林)和甲基膦酸(VX)的O-乙基S-2-(N,N-二异丙基胺)乙基醚,基于具有分子印迹的聚合物,使用有毒化学品的无毒或低毒结构类似物作为模板化合物,特别是:双-2-氯乙基醚(芥子气类似物),甲基膦酸的O-甲基O-异丙基醚(沙林类似物)和甲基膦酸的O-乙基O-2-(N,N-二异丙基胺)乙基醚酸(VX类似物);效果:相对于所选的有毒化学品,所获得的吸附剂具有较高的吸附选择性; 4 cl,3 tbl,3 ex,1 dwg

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