embedded image in which R represents a group chosen from COOH, COOR′, NH2, NHR′ or NR′R″, where R′ and R″ are chosen, independently of one another, from the group of linear or branched alkyl radicals having from 1 to 12 carbon atoms and cycloalkyl radicals having from 3 to 12 carbon atoms, according to which process but-3-ene-1,2-diol (II) is catalytically and selectively oxidized to give 2-oxobut-3-enoic acid (III) and methyl mercaptan is selectively condensed with 2-oxobut-3-enoic acid (III). 2-Oxo-4-methylthiobutyric acid (I), its salts and its derivatives are used as food supplement, in particular in animal nutrition. "/> Synthesis and applications of 2-oxo-4-methylthiobutyric acid, its salts and its derivatives
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Synthesis and applications of 2-oxo-4-methylthiobutyric acid, its salts and its derivatives

机译:2-氧代-4-甲基硫代丁酸,其盐及其衍生物的合成与应用

摘要

The invention relates to a process for preparing 2-oxo-4-methylthiobutyric acid (I), its salts and its derivatives; embedded image in which R represents a group chosen from COOH, COOR′, NH2, NHR′ or NR′R″, where R′ and R″ are chosen, independently of one another, from the group of linear or branched alkyl radicals having from 1 to 12 carbon atoms and cycloalkyl radicals having from 3 to 12 carbon atoms, according to which process but-3-ene-1,2-diol (II) is catalytically and selectively oxidized to give 2-oxobut-3-enoic acid (III) and methyl mercaptan is selectively condensed with 2-oxobut-3-enoic acid (III). 2-Oxo-4-methylthiobutyric acid (I), its salts and its derivatives are used as food supplement, in particular in animal nutrition.
机译:本发明涉及一种制备2-氧代-4-甲基硫代丁酸(I),其盐及其衍生物的方法。 “嵌入式图像” ,其中R代表选自COOH,COOR',NH 2 ,NHR'或NR'R''的基团,其中R'和R”彼此独立地选自具有1至12个碳原子的直链或支链烷基和具有3至12个碳原子的环烷基, 根据丁三烯-1,2-二醇(II)的催化过程和选择性氧化过程,得到2-氧代丁-3-烯酸(III ),然后将甲基硫醇与2-氧代丁-3-烯酸(III)选择性缩合。 2-氧-4-甲基硫代丁酸(I),其盐及其衍生物被用作食品补充剂,尤其是在动物营养中。

著录项

  • 公开/公告号US7662997B2

    专利类型

  • 公开/公告日2010-02-16

    原文格式PDF

  • 申请/专利权人 PATRICK REY;GILBERT BLANCHARD;

    申请/专利号US20050792586

  • 发明设计人 PATRICK REY;GILBERT BLANCHARD;

    申请日2005-12-29

  • 分类号C07C323/52;C07C323/60;C07C319/18;C07C319/20;

  • 国家 US

  • 入库时间 2022-08-21 18:49:44

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