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RUTHENIUM-CONTAINING POLYOXOTUNGSTATES, THEIR PREPARATION AND USE AS CATALYSTS IN THE OXIDATION OF ORGANIC SUBSTRATES
RUTHENIUM-CONTAINING POLYOXOTUNGSTATES, THEIR PREPARATION AND USE AS CATALYSTS IN THE OXIDATION OF ORGANIC SUBSTRATES
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机译:含钌的聚氧钨酸,它们的制备及其在有机碱氧化中的催化作用
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摘要
The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m- or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH-, peroxo, carbonate, NO3-, NO2-, NO-, NH3, amines, F-, Cl-, Br-, I-, SCN-, NCS-, NCO" and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.
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