首页> 外国专利> METHOD OF REGENERATING CATALYTIC ACTIVITY OF SPENT HYDROGEN PROCESSING CATALYST, SPENT HYDROGEN PROCESSING CATALYST WITH REGENERATED ACTIVITY, AND HYDROGEN PROCESSING METHOD

METHOD OF REGENERATING CATALYTIC ACTIVITY OF SPENT HYDROGEN PROCESSING CATALYST, SPENT HYDROGEN PROCESSING CATALYST WITH REGENERATED ACTIVITY, AND HYDROGEN PROCESSING METHOD

机译:特制氢处理催化剂的再生催化活性的方法,具有再生活性的制氢催化剂和制氢方法

摘要

FIELD: chemistry.;SUBSTANCE: present invention relates to a method of regenerating catalytic activity of a spent hydrogen processing catalyst which does not contain an additive. A method is described for regenerating catalytic activity of a spent hydrogen processing catalyst which does not contain an additive (versions), which involves: bringing a spent non-additive containing hydrogen processing catalyst which contains a metal component and carrier material, which has low catalytic activity with respect to the catalyst in fresh state before its use, which results in the catalyst being spent, with a solution, where the said solution contains a chelating agent chosen from a group of compounds consisting of amino carboxylic acids, and a solvent, and where said contacting takes place in a period of time longer than 10 hours, with provision for regenerated catalytic activity, obtaining old catalyst containing said chelating agent and said solvent, where said spent hydrogen processing catalyst contains amount of said chelating agent in the interval from 0.005 mole of chelating agent per mole of active metal to 1 mole of chelating agent per mole of active metal; keeping said old catalyst in conditions which include drying temperature so as to remove part of said solvent from said old catalyst with removal of not less than 50 wt % of said chelating agent from said old catalyst, obtaining dried old catalyst as a resu and treatment of said dried old catalyst with sulphur, obtaining regenerated catalyst. Also described is a catalyst produced using methods described above and hydrogen processing method, involving bringing hydrocarbon starting material in hydrogen processing conditions with a catalyst produced using methods described above.;EFFECT: higher degree of regenerated catalytic activity of spent hydrogen processing catalyst.;19 cl, 2 tbl, 2 ex
机译:再生废氢处理催化剂的催化活性的方法技术领域本发明涉及再生不含添加剂的废氢处理催化剂的催化活性的方法。描述了一种用于再生不包含添加剂(版本)的废氢处理催化剂的催化活性的方法,该方法包括:引入包含金属成分和载体材料的废非添加剂含氢处理催化剂,该催化剂具有较低的催化活性。在使用前对新鲜状态下的催化剂的活性,这导致催化剂在溶液中消耗,其中所述溶液包含选自由氨基羧酸和溶剂组成的组的螯合剂,以及溶剂;和其中所述接触在大于10小时的时间段内进行,提供再生的催化活性,获得包含所述螯合剂和所述溶剂的旧催化剂,其中所述废氢处理催化剂包含所述螯合剂的量为0.005之间每摩尔活性金属1摩尔螯合剂对每摩尔活性金属1摩尔螯合剂;将所述旧催化剂保持在包括干燥温度的条件下,以便从所述旧催化剂中除去部分所述溶剂,同时从所述旧催化剂中去除不少于50wt%的所述螯合剂,结果得到干燥的旧催化剂;用硫处理所述干燥的旧催化剂,得到再生催化剂。还描述了使用上述方法生产的催化剂和氢气处理方法,包括将烃类原料与使用上述方法生产的催化剂置于氢气处理条件下;效果:废氢气处理催化剂的再生催化活性更高; 19 cl,2 tbl,2前

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