process for the production of fibres with ultrahohem molecular weight polyethylene

摘要

A process for producing fiber of ultra high molecular weight polyethylene, with flat cross-section and high cohesiveness, is disclosed. The process includes: distributing the powder of UHMW-PE into the solvent evenly; preparing an uniform mixed emulsion by properly untangling with a high shear; at the same time adding the polar polymer comprising polar groups, for example a carboxyl group, a carbonyl group, an ether group, or an ester group and so on; evenly distributing the polar polymer together with the polyethylene powder in the solvent to form an uniform mixed emulsion; forming a gel filament with the mixed emulsion by gel spinning method, then extracting, drying, and ultra drafting so as to obtain the said UHMW-PE fiber, with falt cross section, high strength and cohesiveness. By properly untangling, the swellability and dissolubility of the ultra high molecular weight polyethylene can be accelerated, while the polar polymer being evenly distributed therein can significantly improve the adhesive capacity of the fiber. The operations in the production method are easy, and furthermore, time, labor and cost can be saved. The section of the fiber is of a flat rectangle shape and the wall is thin and even, so the path for the solvent in the fiber diffusing out of the gel filament can be significantly shorten, and thus the efficiency of extraction and the uniformity of the fiber can be improved.