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ORGANIC CALCIUM PHOSPHATE PRECURSOR AND CALCIUM PHOSPHATE POWDER, CERAMIC STRUCTURE AND METHOD FOR PRODUCING THEM

机译:有机磷酸钙前体和磷酸钙粉末,陶瓷结构及其制备方法

摘要

PROBLEM TO BE SOLVED: To solve, on the synthesis of calcium phosphate, the problems of a conventional complex polymerization method wherein: the precursor has a very stable structure because of using large amounts of organic compounds including a polymerizing agent and a complexing agent on the production of the precursor, and the precursor must thermally be decomposed at high temperature, when the precursor is used to synthesize the calcium phosphate; since the powder obtained by the calcination of the precursor is easily coagulated, a calcium phosphate coating film obtained by coating a substrate with the powder does not become compacted; and a large amount of carbon dioxide exhausted on the thermal decomposition of an organic solvent gives loads to the environments in a non-neglected degree; and the like.;SOLUTION: The method for producing the organic calcium phosphate precursor, includes reacting a phosphorus-containing chelating agent having a phosphono group and a carboxyl group with a calcium ion-containing calcium compound in a solvent in a calcium/phosphorus molar ratio of 1.50 to 1.67 to produce the organic calcium phosphate precursor.;COPYRIGHT: (C)2011,JPO&INPIT
机译:解决的问题:为了解决磷酸钙的合成中的常规络合聚合方法的问题,其中:由于在该前体上使用了大量的有机化合物,包括聚合剂和络合剂,因此该前体具有非常稳定的结构。生产前体,并且当该前体用于合成磷酸钙时,该前体必须在高温下热分解;由于通过前体的煅烧而得到的粉末容易凝集,因此通过将粉末涂布在基材上而得到的磷酸钙涂膜不会致密化。通过有机溶剂的热分解而排出的大量二氧化碳以不容忽视的程度给环境带来了负担;解决方案:制备有机磷酸钙前体的方法包括使具有膦酰基和羧基的含磷螯合剂与含钙离子的钙化合物在钙/磷摩尔中在溶剂中反应。以1.50:1.67的比例生产有机磷酸钙前体。;版权所有:(C)2011,日本特许厅&INPIT

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