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Compound having an electron transport properties or electroluminescent characteristics

机译:具有电子传输特性或电致发光特性的化合物

摘要

Compound (CR 3 = CR 4) nAr of (CR 4 = CR 3)n R 2, wherein, n is 1 or 0 the formula R 1, Ar may be a combination of condensation and chain fused or chain or shows the aryl or heteroaryl having an aromatic ring of 1-5, well, in the case of a five-membered ring, which alkoxy terrorism atoms or aryl, fluoro, fluoro to nitrogen is substituted alkoxy, fluoro, cyano or fluoroalkyl Well is N substituted by aryl which is optionally further substituted by cyano or alkyl; R 2 and R 1 are independently a nitrogen or an aryl having a fused aromatic ring of 2 to 4, a sulfur-containing heteroaryl or an oxygen , one of which is a five-membered ring well, and is optionally substituted by aryl or heteroaryl having a condensed aromatic ring or a chain of 1 to 5, which may be further substituted alkoxy, fluoro, cyano or fluoroalkyl well; R 3 and R 4 is hydrogen, methyl, ethyl or benzyl independently. A method of producing a compound having an electron-conductive properties and electroluminescent properties and / or is provided, which is further substituted by an aryl or heteroaryl having an aromatic ring of 1 to 4 or unsubstituted, aromatic dialdehyde includes be fused with heteroaryl compounds are methyl-substituted with a ring fused 2-4 may, substituents or heterocyclyl substituents or the aryl optionally fluoro one or more cyano substituents or fluoroalkyl be replaced. Under reflux, the condensation is carried out in acetic anhydride. The compounds can be incorporated into the electrostatic imaging member that a high electron mobility, and provides life and good low turn-on voltage in accordance with an embodiment or can for example be incorporated in the optical light-emitting diode as an electron transport layer. Compositions comprising the dopant is provided with at least one electron transport material and a second or host compounds and / or above.
机译:(CR 4 = CR 3) n <的化合物(CR 3 = CR 4) nAr / Sub> R 2,其中,n为1或0式 R 1 Ar可以是缩合和链稠或链的组合,或表示芳基或杂芳基芳香环为1-5的环,在五元环的情况下,烷氧基恐怖主义原子或芳基,氟,氟至氮为取代的烷氧基,氟,氰基或氟代烷基。任选地进一步被氰基或烷基取代; R 2 和R 1 独立地为氮或具有2至4的稠合芳环的芳基,含硫的杂芳基或氧,其中之一为五元环孔,并且任选地被具有稠合的芳环或1至5链的芳基或杂芳基取代,该芳基或杂芳基可以进一步被取代为烷氧基,氟,氰基或氟烷基。 R 3 R 4 分别为氢,甲基,乙基或苄基。提供了一种制备具有电子导电性能和电致发光性能的化合物的方法和/或,其进一步被具有1-4个芳环的芳基或杂芳基或未取代的芳族二醛取代,包括与杂芳基化合物稠合的方法。被稠合的2-4取代的甲基取代的取代基或杂环基取代基或任选地为氟的芳基是一个或多个氰基取代基或氟代烷基。在回流下,缩合在乙酸酐中进行。根据一个实施方案,可以将这些化合物并入具有高电子迁移率并提供寿命和良好的低导通电压的静电成像部件中,或者例如可以将其作为电子传输层并入光学发光二极管中。包含掺杂剂的组合物具有至少一种电子传输材料和第二或主体化合物和/或以上。

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