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Process for obtaining hybrid catalysts complex compounds of transition metal nanoparticles encapsulated in porous silica, titania or zirconia.

机译:获得杂化催化剂的方法,其包封在多孔二氧化硅,二氧化钛或氧化锆中的过渡金属纳米粒子的复合物。

摘要

Process for obtaining hybrid catalysts complex compounds of transition metal nanoparticles encapsulated in porous silica, titania or zirconia.; The present invention describes a chemically stable hybrid catalyst system comprising silica nanoparticles, titania or zirconia unfunctionalized and an organometallic complex of a transition metal. In the new materials described the catalytic species are encapsulated in the polymer matrix by direct interaction with it, without adding liniers or functional groups. a method of preparation is also described in a single step by the sol-gel by hydrolysis and condensation of alkoxides of Si, Ti or Zr in a medium, to which is added the organometallic complexes of transition metals while the hydrolysis / condensation of alkoxide occurs. These catalyst systems are used in the synthesis of organic compounds, chemical and pharmaceutical industry.
机译:获得杂化催化剂的方法,所述方法包封在多孔二氧化硅,二氧化钛或氧化锆中的过渡金属纳米粒子的复合化合物。本发明描述了化学稳定的杂化催化剂体系,其包含二氧化硅纳米粒子,未官能化的二氧化钛或氧化锆以及过渡金属的有机金属配合物。在所描述的新材料中,催化物种通过与之直接相互作用而被封装在聚合物基质中,而不添加衬里或官能团。还描述了一种制备方法,该方法通过溶胶-凝胶在介质中水解和缩合Si,Ti或Zr的醇盐来一步制备,向其中加入过渡金属的有机金属络合物,同时发生醇盐的水解/缩合。 。这些催化剂体系用于有机化合物的合成,化学和制药工业。

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