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ORGANOMETALLIC COMPLEXES AS HYDROGEN STORAGE MATERIALS AND A METHOD OF PREPARING THE SAME

机译:有机复合物作为储氢材料及其制备方法

摘要

The present invention relates to an organic-transition metal complex which can safely and reversibly store hydrogen in a high capacity, and a process for preparing the same. In order to achieve the objects, the hydrogen storage material according to the invention comprises a complex generated by combination of an organic substance containing a hydroxyl (-OH) group(s) with a transition metal containing compound, which can more effectively store hydrogen with more than one transition metal being bonded per molecule. Examples of the organic substances containing hydroxyl (-OH) group(s) include alkyl derivatives such as ethylene glycol, trimethylene glycol and glycerol, and hydroxyl-containing aryl derivatives such as fluoroglucinol. As the transition metal, titanium (Ti), vanadium (V) and scandium (Sc), which can make Kubas binding, may be mentioned.
机译:有机过渡金属络合物及其制备方法技术领域本发明涉及一种能够安全且可逆地高容量地储存氢的有机过渡金属络合物及其制备方法。为了实现这些目的,根据本发明的储氢材料包括通过将含有羟基(-OH)的有机物质与含有过渡金属的化合物结合而生成的配合物,该配合物可以更有效地将氢与每个分子键合一种以上的过渡金属。含有羟基(-OH)的有机物质的实例包括烷基衍生物,例如乙二醇,三亚甲基二醇和甘油,以及含羟基的芳基衍生物,例如氟葡萄糖醇。作为过渡金属,可以提及可以使Kubas结合的钛(Ti),钒(V)和scan(Sc)。

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