首页> 外国专利> METHOD FOR PRODUCING LITHIUM ADSORBENT, LITHIUM ADSORBENT, STARTING MATERIALS FOR LITHIUM ADSORBENT, LITHIUM CONCENTRATION METHOD, AND LITHIUM CONCENTRATION DEVICE

METHOD FOR PRODUCING LITHIUM ADSORBENT, LITHIUM ADSORBENT, STARTING MATERIALS FOR LITHIUM ADSORBENT, LITHIUM CONCENTRATION METHOD, AND LITHIUM CONCENTRATION DEVICE

机译:锂吸附剂的制造方法,锂吸附剂,锂吸附剂的原料,锂浓缩法及锂浓缩装置

摘要

Provided is a method for producing a lithium adsorbent, which is used in the industrial concentration and recovery of trace amounts of lithium contained in lithium-containing water, and which has excellent selective absorbency and high adsorption speed, has a high weight/adsorption ratio, and is capable of repeated adsorption and elution. The method comprises: a mechanochemical step for mixing trimanganese tetraoxide and lithium hydroxide such that the molar ratio of manganese (x) and lithium (y) is x:y = 1:1 to 1.5:1, and subjecting the mixture to mechanochemical pulverization; a pre-calcining step for then pre-calcining in a temperature range of 375ºC to 450ºC in air or an oxygen atmosphere; a calcining step for then cooling, mixing, and pulverizing, followed by calcining in a temperature range of 475ºC to 550ºC in air or an oxygen atmosphere in order to obtain a spinel-type lithium manganate with excess oxygen; and an elution step for eluting lithium by treating the spinel-type lithium manganate with excess oxygen using an acid in an amount that is in large excess with respect to the amount of lithium.
机译:提供了一种锂吸附剂的制造方法,其用于工业浓缩和回收含锂水中所含的痕量锂,并且具有优异的选择性吸收性和高吸附速度,具有高的重量/吸附比,并能够重复吸附和洗脱。该方法包括:机械化学步骤,用于混合四氧化三锰和氢氧化锂,以使锰(x)与锂(y)的摩尔比为x:y = 1:1至1.5:1,并对混合物进行机械化学粉碎。预煅烧步骤,然后在空气或氧气气氛中于375ºC至450ºC的温度范围内进行预煅烧;煅烧步骤,然后冷却,混合和粉碎,然后在空气或氧气气氛中于475℃至550℃的温度范围内煅烧,以获得具有过量氧气的尖晶石型锰酸锂;洗脱步骤是通过使用相对于锂的量大大过量的酸用过量的氧处理尖晶石型锰酸锂来洗脱锂。

著录项

相似文献

  • 专利
  • 外文文献
  • 中文文献
获取专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号