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PROCESS FOR PRODUCTION OF GLYCIDYL ETHER COMPOUNDS, AND MONOALLYL MONOGLYCIDYL ETHER COMPOUND

机译:缩水甘油醚化合物和单烯丙基单缩水甘油醚化合物的生产方法

摘要

Provided are: a process by which a compound having an allyl ether linkage can be efficiently converted into the corresponding glycidyl ether compound under mild conditions using hydrogen peroxide as the oxidizing agent; and a novel monoallyl monoglycidyl ether compound having a biphenyl skeleton. Specifically provided are: a process for the production of glycidyl ether compounds which comprises reacting a compound having an allyl ether linkage with hydrogen peroxide to epoxidize the carbon-carbon double bond of the allyl group and thus form the corresponding glycidyl ether compound, characterized by using, as the reaction catalyst, a tungsten compound, a tertiary amine, and phenylphosphonic acid; and a monoallyl monoglycidyl ether compound having a biphenyl skeleton. The monoallyl monoglycidyl ether compound can be produced by the process.
机译:提供:一种方法,通过该方法可以在温和的条件下使用过氧化氢作为氧化剂将具有烯丙基醚键的化合物有效地转化为相应的缩水甘油醚化合物;具有联苯骨架的新型单烯丙基单缩水甘油醚化合物。具体地提供:一种生产缩水甘油醚化合物的方法,该方法包括使具有烯丙基醚键的化合物与过氧化氢反应以环氧化烯丙基的碳-碳双键,从而形成相应的缩水甘油醚化合物,其特征在于使用作为反应催化剂,钨化合物,叔胺和苯基膦酸。具有联苯骨架的单烯丙基单缩水甘油醚化合物。单烯丙基单缩水甘油基醚化合物可以通过该方法制备。

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