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Signal processing method of the NMR apparatus for a particular relaxation time

机译:特定弛豫时间的NMR设备的信号处理方法

摘要

PROBLEM TO BE SOLVED: To provide a method for calculating the relaxation time of each of spectrum peaks from the FID signal of a sample obtained by the measurement of NMR, a method for realizing the assignment of a spectrum to a molecule from the difference of the relaxation time in a mixed solution and a method for monitoring a measuring environment from the relaxation time of each of the calculated spectra.;SOLUTION: (N) duplications of an observed FID signal are formed while the processing defined by numerical formulae exp(-t/τ') and τ'(i)=τ0+Δi is applied to the duplicated FID signal data and spectrum processing is performed with respect to all of the duplicated FID signals. Thereafter, the relaxation time defined by the numerical formula: τ'(i)=τ0+Δi making the height of each of the frequency components of the duplicated FID signals half the height of the observed FID signal is recorded to form the set data of frequency and τ'. Frequency is set as an axis to detect a peak with respect to the obtained set data gathering of the frequency and τ' to specify the relaxation time at every observation spectrum of NMR.;COPYRIGHT: (C)2007,JPO&INPIT
机译:要解决的问题:提供一种用于根据通过NMR测量获得的样品的FID信号来计算每个光谱峰的弛豫时间的方法,以及一种根据光谱的差异实现光谱分配给分子的方法。混合溶液中的弛豫时间以及从每个计算出的光谱的弛豫时间监视测量环境的方法;解决方案:在用数值公式exp(-t定义)进行处理时,形成了(N)个观察到的FID信号的重复项&和'(i)=) 0 +Δi应用于复制的FID信号数据,并对所有复制的FID信号进行频谱处理。此后,由数值公式定义的弛豫时间:&'(i)=& 0 +Δ i使复制的FID信号的每个频率分量的高度都为记录观察到的FID信号以形成频率和τ的设定数据。将频率设置为轴,以相对于所获得的频率和“ t”的设置数据收集来检测峰值。指定在每个NMR观察光谱下的弛豫时间。;版权所有:(C)2007,JPO&INPIT

著录项

  • 公开/公告号JP5006524B2

    专利类型

  • 公开/公告日2012-08-22

    原文格式PDF

  • 申请/专利权人 株式会社日立製作所;

    申请/专利号JP20050140890

  • 发明设计人 北川 功;

    申请日2005-05-13

  • 分类号G01N24/08;

  • 国家 JP

  • 入库时间 2022-08-21 17:39:50

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