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Bipyridine compound, transition metal complex, and method for production of conjugated aromatic compound using the transition metal complex

机译:联吡啶化合物,过渡金属络合物以及使用该过渡金属络合物制备共轭芳族化合物的方法

摘要

A bipyridine compound represented by the formula (1):; embedded image wherein R1, R2 and R3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R4, R5, R6, R7 and R8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.
机译:由式(1)表示的联吡啶化合物: “嵌入式图像” 其中R 1 ,R 2 和R 3 分别独立地表示可以被取代的C1-C10烷基等,R 4 ,R 5 ,R 6 ,R 7 和R 8 分别独立表示一个氢原子等,通过使式(1)表示的联吡啶化合物与属于第9、10或11族的过渡金属的化合物接触而得到的过渡金属络合物,以及使反应进行反应的共轭芳香族化合物的制造方法结构上与上述芳香族化合物(A)具有相同结构的芳香族化合物(A)或芳香族化合物(B)在结构上与芳香族环键合有1个或2个离去基团的芳香族化合物(A)在过渡金属络合物的存在下,与上述芳族化合物(A)不同的是具有与芳族环键合的一个或两个离去基团。

著录项

  • 公开/公告号US8293905B2

    专利类型

  • 公开/公告日2012-10-23

    原文格式PDF

  • 申请/专利权人 TAKU ASAUMI;TAKASHI KAMIKAWA;

    申请/专利号US20080664960

  • 发明设计人 TAKASHI KAMIKAWA;TAKU ASAUMI;

    申请日2008-06-18

  • 分类号C07F7/02;C07D213/22;

  • 国家 US

  • 入库时间 2022-08-21 17:30:40

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