SPECTROSCOPY OF TRANSITION METAL SPECIES IN RARE GAS MATRICES I. Vanadium metal II. Sulfides III. Carbonyl complexes IV. Dinitrogen complexes V. Homonuclear diatomic compounds

摘要

The spectrum of V isolated in Ar and Kr matrices at 10°K has been correlated with the gas phase spectrum. The electron configuration was found to be a major factor in determining the direction and the magnitude of the matrix shift for this system. A model calculation was performed using extended Hlickel theory. A plausible explanation for the origin of the matrix shifts and the altered intensity relationships observed in the •matrix has been developed.