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Method of processing polyaniline, particularly for medicinal and bioengineering applications

机译:加工聚苯胺的方法,特别是用于医药和生物工程应用

摘要

The method of preparing polyaniline of the present invention is characterized in that already prepared basic form of polyaniline phase is reprotonated by suspending thereof in an aqueous solution of an organic or inorganic acid having pH value less than 3 to obtain a reprotonated salt. After isolation, the reprotonated salt is subjected to deprotonation by suspending thereof in an aqueous solution of an organic or inorganic base having pH value higher than 9 to obtain a re-deprotonated base wherein the reprotonation and deprotonation phases are repeated in alternating manner. Hydrochloric acid, phosphoric acid, methanesulfonic acid, nitric acid, tetrafluoroboric acid can be used for instance as acid and ammonium hydroxide, sodium hydroxide, potassium hydroxide can be used as an inorganic base and hydroxylamine as an organic base.
机译:本发明的制备聚苯胺的方法的特征在于,通过将已经制备的碱性形式的聚苯胺相悬浮在pH值小于3的有机或无机酸的水溶液中而使之质子化,从而获得质子化的盐。分离后,通过将重质子化的盐悬浮在pH值高于9的有机或无机碱的水溶液中而使其去质子化,从而获得重去质子化的碱,其中以交替方式重复质子化和去质子化相。可以使用例如盐酸,磷酸,甲磺酸,硝酸,四氟硼酸作为酸,并且可以将氢氧化铵,氢氧化钠,氢氧化钾用作无机碱,并且将羟胺用作有机碱。

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