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METHOD FOR PRODUCING CRYSTALLINE SILICON OF PHOTOELECTRIC QUALITY BY ADDITION OF DOPING IMPURITIES AND PHOTOELECTRIC ELEMENT

机译:掺杂杂质和光电子元素的合成制备光电子晶体硅的方法

摘要

1. A silicon-based photovoltaic cell, characterized in that silicon contains a concentration of donor alloying elements and / or acceptor alloying elements greater than or equal to 5 atomic parts per million, and the difference between these two concentrations is less than or equal to 5 atomic parts / million ! 2. The photovoltaic cell according to claim 1, characterized in that the concentration of boron is greater than or equal to 5 at.h / million ! 3. The photovoltaic cell according to claim 1, characterized in that the concentration of phosphorus is greater than or equal to 5 at.h / million ! 4. A method of producing crystalline silicon of photoelectric quality by crystallization of molten silicon raw materials, characterized in that the sum of the initial concentrations of donor alloying elements and acceptor alloying elements in silicon raw materials is greater than 0.1 at.h / million, the concentration of both acceptor and donor alloying elements are less than 25 at. ppm, and the method includes before crystallization of silicon:! - determination of the concentrations of alloying substances of the donor type and acceptor type, originally present in the raw material,! - adding at least a predetermined amount of dopant with a distribution coefficient of less than 0.1 to satisfy at least 50% of crystallized silicon from the start of crystallization, or the first equation for p-type crystalline silicon! ! or the second equation for n-type crystalline silicon! ! moreover, in these equations! - k a, k d correspond to the distribution coefficients of acceptor alloying elements and donor alloying elements, respectively! - C 0a, C 0d correspond to the end�
机译:1.一种基于硅的光伏电池,其特征在于,硅包含的施主合金元素和/或受体合金元素的浓度大于或等于百万分之5原子份,并且这两个浓度之间的差小于或等于5原子份/百万! 2.根据权利要求1所述的光伏电池,其特征在于,硼的浓度大于或等于5at.h /百万million。 3.根据权利要求1所述的光伏电池,其特征在于,磷的浓度大于或等于5at.h /百万!。 4.一种通过熔融硅原料的结晶生产具有光电质量的结晶硅的方法,其特征在于,硅原料中供体合金元素和受体合金元素的初始浓度之和大于0.1 at.h /百万,受主和供体合金元素的浓度均小于25 at。 ppm,并且该方法包括在结晶硅之前: -确定原材料中最初存在的供体类型和受体类型的合金物质的浓度! -从结晶开始就添加至少预定量的掺杂剂,其分布系数小于0.1,以满足至少50%的结晶硅,或p型结晶硅的第一方程式! !或n型晶体硅的第二个方程! !而且,在这些等式中! -k a,k d分别对应于受体合金元素和施主合金元素的分布系数! -C 0a,C 0d对应于末尾。

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