首页> 外国专利> CATALYST FOR USE IN HYDROTREATMENT COMPRISING METALS OF GROUP VIII AND VIB AND PREPARATION WITH CITRIC ACID AND C1-C4 DIALKYL SUCCINATE

CATALYST FOR USE IN HYDROTREATMENT COMPRISING METALS OF GROUP VIII AND VIB AND PREPARATION WITH CITRIC ACID AND C1-C4 DIALKYL SUCCINATE

机译:用于加氢处理第VIII和VIB族金属的催化剂,并用柠檬酸和C1-C4丁二酸二辛酯制备

摘要

The invention relates to a catalyst comprising an alumina-based amorphous support, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydro-dehydrogenating function comprising at least one element. Group VIII and at least one element of Group VIB, a catalyst whose Raman spectrum comprises the most intense bands characteristic of Keggin heteropolyanions (974 and / or 990 cm), C1-C4 dialkyl succinate and citric acid (including 785 and 956 cm). The invention also relates to the process for preparing said catalyst in which a catalyst precursor in the dried, calcined or regenerated state containing the elements of the hydro-dehydrogenating function, optionally phosphorus, is impregnated with an impregnation solution comprising at least one a C1-C4 dialkyl succinate, citric acid and optionally at least one phosphorus compound and optionally acetic acid, and is then dried. The invention also relates to the use of this catalyst in any hydrotreatment process.
机译:本发明涉及一种催化剂,该催化剂包含氧化铝基无定形载体,琥珀酸C1-C4二烷基酯,柠檬酸和任选的乙酸,磷以及具有至少一种元素的加氢脱氢功能。 VIII族和VIB族的至少一种元素,其拉曼光谱包括Keggin杂多阴离子(974和/或990cm),C 1 -C 4琥珀酸二烷基酯和柠檬酸(包括785和956cm)的最强的带特征的催化剂。本发明还涉及制备所述催化剂的方法,其中用包含至少一种C 1-的浸渍溶液浸渍处于干燥,煅烧或再生状态的包含加氢脱氢功能的元素,任选地磷的催化剂前体。琥珀酸C4二烷基酯,柠檬酸和任选的至少一种磷化合物和任选的乙酸,然后干燥。本发明还涉及该催化剂在任何加氢处理过程中的用途。

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