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Phospho knight content catalyst null i. general formula (i)

机译:磷骑士含量催化剂无效i。通式(i)

摘要

Discloses a catalyst solution for the preparation of aldehydes having an aldehyde ratio - aldehyde to iso - comprising phosphonite more ligands, the hydroformylation solvent and rhodium, or various normal one. Also, comprising a phosphonite that more ligands, is contacted with the hydroformylation solvent and one or rhodium, olefin, hydrogen and carbon monoxide, various normal - aldehyde with aldehyde ratio - iso aldehyde to I also disclosed a manufacturing method. By varying the process variables more or one including the partial pressure of carbon monoxide, the ligand and temperature (gram moles) to rhodium (gram atom), a catalyst solution as a base material phosphonite, n - aldehyde to It is possible to manipulate the aldehyde ratio - iso.
机译:公开了一种用于制备醛的催化剂溶液,所述醛溶液具有醛比-醛与异-醛的比例,其包含亚膦酸酯,更多的配体,加氢甲酰化溶剂和铑,或各种常规的配体。而且,还公开了包含更多配体的亚膦酸酯与加氢甲酰化溶剂以及铑,烯烃,氢和一氧化碳中的一种,或铑,烯烃,氢和一氧化碳接触的各种正-醛与醛比率-异醛。通过改变一个或多个过程变量,包括一氧化碳的分压,配体和相对于铑的温度(克摩尔)(克原子),作为基础材料的催化剂溶液,亚膦酸酯,正醛,可以控制醛比率-iso。

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