首页> 外国专利> METHOD FOR MANUFACTURING CORE-SHELL TYPE SUPPORTED CATALYSTS AND CORE-SHELL TYPE SUPPORTED CATALYSTS FORMED THEREBY

METHOD FOR MANUFACTURING CORE-SHELL TYPE SUPPORTED CATALYSTS AND CORE-SHELL TYPE SUPPORTED CATALYSTS FORMED THEREBY

机译:制造核心-壳型支撑催化剂的方法和由此形成的核心-壳型支撑催化剂

摘要

A method for manufacturing a core-shell type supported catalyst, wherein alloy particles having a core-shell structure with a different interior and exterior are supported on a complex carbon support. The method includes: 1) dissolving and dispersing a carbon support in a solvent using a stabilizer; 2) dissolving a core precursor in the solution, and adding a strong reducing agent to reduce and support a transition metal of the core precursor on a surface of the carbon support; 3) filtering and washing the carbon support on which the transition metal is supported; 4) re-dispersing the filtered and washed carbon support in a shell precursor aqueous solution; and 5) adding a weak reducing agent to the solution of step 4) at 60˜80° C. so that metal ions of a shell precursor are selectively reduced and deposited on the transition metal.
机译:一种核-壳型负载型催化剂的制造方法,其中,将具有内部和外部不同的核-壳结构的合金颗粒负载在复合碳载体上。该方法包括:1)使用稳定剂将碳载体溶解并分散在溶剂中; 2)将核心前体溶解在溶液中,并添加强还原剂以将核心前体的过渡金属还原并负载在碳载体的表面上; 3)过滤并洗涤负载有过渡金属的碳载体; 4)将过滤和洗涤过的碳载体再分散在壳前体水溶液中; 5)在60〜80℃下向步骤4)的溶液中加入弱还原剂,使壳前体的金属离子被选择性还原并沉积在过渡金属上。

著录项

  • 公开/公告号US2013150235A1

    专利类型

  • 公开/公告日2013-06-13

    原文格式PDF

  • 申请/专利权人 BUM WOOK ROH;

    申请/专利号US201213531818

  • 发明设计人 BUM WOOK ROH;

    申请日2012-06-25

  • 分类号B01J21/18;B01J23/755;B01J23/745;B01J23/44;B01J23/42;B01J23/75;B82Y40;

  • 国家 US

  • 入库时间 2022-08-21 16:52:40

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