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Cyclic Carbonate-Modified Siloxane Process for Producing the Same Non-Aqueous Electrolytic Solution Secondary Battery and Capacitor
Cyclic Carbonate-Modified Siloxane Process for Producing the Same Non-Aqueous Electrolytic Solution Secondary Battery and Capacitor
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机译:环状碳酸酯改性的硅氧烷工艺生产相同的非水电解液二次电池和电容器
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摘要
Cyclic carbonate modified siloxane represented by following formula (1).; Formula 1 ;R 1a A b SiO (4-ab) / 2;In formula, R 1 is the same or heterogeneous selected from a hydroxyl group and a C1-C30 alkyl group which may be substituted by a halogen atom, an aryl group, an aralkyl group, an amino substituted alkyl group, a carboxyl substituted alkyl group, an alkoxy group, an aryloxy group. It is a monovalent group, A is a cyclic carbonate group represented by following formula (2). a and b are positive numbers of 1.0 = a = 2.5 and 0.001 = b = 1.5, respectively, and a + b is 1.001 = a + b = 3. End, [R 1 ASiO 2/2 ] The number of units, other than three or less straight chain siloxane and silicon atoms of 3 to 6 cyclic siloxane case.;Formula 2;The battery using the nonaqueous electrolyte containing the cyclic carbonate-modified siloxane of the present invention has excellent temperature characteristics and cycle characteristics.;Cyclic carbonate modified siloxane, nonaqueous electrolyte, secondary battery, capacitor
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机译:由下式(1)表示的环状碳酸酯改性的硅氧烷。; <式1>; R 1 Sup> a Sub> A b Sub> SiO (4 -ab)/ 2 Sub>;式中,R Sup> 1> Sup>是选自羟基和可被卤素原子取代的C1-C30烷基的相同或不相同的基团,芳基,芳烷基,氨基取代的烷基,羧基取代的烷基,烷氧基,芳氧基。 A为一价基团,A为下式(2)表示的环状碳酸酯基。 a和b分别是1.0 <= a <= 2.5和0.001 <= b <= 1.5的正数,并且a + b是1.001 <= a + b <=3。 End,[R 1 ASiO 2/2 Sub> Sup>],三个或更少的直链硅氧烷和3到6个环状硅氧烷的硅原子单元数; <式2>;使用非水电解质的电池含有本发明的环状碳酸酯改性的硅氧烷具有优异的温度特性和循环特性。环状碳酸酯改性的硅氧烷,非水电解质,二次电池,电容器
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