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FULLERENE C60 DERIVATIVE, AND RESIST COMPOSITION FOR EXTREME ULTRAVIOLET LIGHT OR ELECTRON BEAM EXPOSURE
FULLERENE C60 DERIVATIVE, AND RESIST COMPOSITION FOR EXTREME ULTRAVIOLET LIGHT OR ELECTRON BEAM EXPOSURE
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机译:富勒烯C60的衍生物和极紫外光或电子束曝光的抗蚀剂组合物
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摘要
PROBLEM TO BE SOLVED: To provide a novel fullerene C60 derivative which has excellent solubility with a solvent used for a resist and has low electron accepting property, and when used as a base component of a resist composition for lithography using EUV light or EB, which gives the resist composition having high sensitivity without inhibiting generation of an acid by an acid generator.;SOLUTION: The fullerene C60 derivative is represented by formula (1) below. In the formula, the structure represented by FLN enclosed by a circle represents a C60 fullerene skeleton; R1 represents a hydrogen atom or a hydrocarbon group having 1 to 24 carbon atoms; R2 represents an aromatic group having a phenolic hydroxyl group; Rx represents a hydrogen atom, a hydroxyl group or an organic group having 1 to 24 carbon atoms; n is an even number of 2 to 12; and a plurality of Rx may be connected to each other to form a group coupling with two carbon atoms on the fullerene skeleton.;COPYRIGHT: (C)2014,JPO&INPIT
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机译:解决的问题:提供新颖的富勒烯C 60 Sub>衍生物,其与用于抗蚀剂的溶剂具有优异的溶解性并且具有低的电子接受性,并且当用作用于抗蚀剂组合物的基础组分时,使用EUV光或EB进行光刻,可以使抗蚀剂组合物具有高感光度而不会抑制酸产生剂产生酸。解决方案:富勒烯C 60 Sub>衍生物由下式(1)表示。式中,以FLN表示的结构用圆包围表示C 60 Sub>富勒烯骨架。 R 1 Sup>代表氢原子或具有1至24个碳原子的烃基; R 2 Sup>表示具有酚性羟基的芳香族基团。 R x Sup>表示氢原子,羟基或碳数1〜24的有机基团。 n是2到12的偶数;多个R x Sup>可以相互连接形成在富勒烯骨架上与两个碳原子偶合的基团。;版权:(C)2014,JPO&INPIT
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