Method for producing thin self-supporting metal oxide ceramic, metal oxide ceramic, fuel cell, high temperature electrolysis cell, measuring device and / or detecting device, and method of use

摘要

The present invention relates to a method for manufacturing a metal-oxide-based ceramic, including, in order, the step of inserting, into a flash sintering device, a nanocrystalline powder comprising crystallites and crystallite agglomerates of a ceramic of formula, Zr1-xMxO2, where M is chosen from yttrium, scandium and cerium, or Ce1-xM'xO2, where M' is chosen from gadolinium, scandium, samarium and yttrium, where x lies between 0 and 0.2, the powder having an average crystallite size of between 5 and 50 nm, an average crystallite agglomerate size of between 0.5 and 20 mum, and a specific surface area of between 20 and 100 m2/g. The invention further includes the step of flash sintering the powder by applying a pressure of between 50 and 150 MPa, at a temperature of between 850° C. and 1400° C., for a time of between 5 and 30 minutes.