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Method Of Forming Polysilanes And Polycarbosilanes In The Presence Of A Metal Silicide

机译:在金属硅化物存在下形成聚硅烷和聚碳硅烷的方法

摘要

A mixture of at least one polysilane and at least one polycarbosilane is formed in the presence of a metal silicide. The mixture is formed utilizing a method that includes the step of combining the metal silicide and an alkyl halide in a reactor at a temperature of from 200° C. to 600° C. The alkyl halide has the formula RX, wherein R is C1-C10 alkyl and X is halo. This method forms high yield mixtures of the at least one polysilane and the at least one polycarbosilane. Additionally, the mixture is time and cost effective and allows the mixture to be formed in a predictable and controlled manner. Moreover, the components used in this method can be easily recycled and/or re-used in other processes.
机译:在金属硅化物的存在下形成至少一种聚硅烷和至少一种聚碳硅烷的混合物。使用包括以下步骤的方法形成混合物:在反应器中在200℃至600℃的温度下合并金属硅化物和烷基卤化物。烷基卤化物具有式RX,其中R为C < Sub> 1 -C 10 烷基,X是卤素。该方法形成了至少一种聚硅烷和至少一种聚碳硅烷的高产率混合物。另外,混合物是时间和成本有效的,并且允许以可预测的和受控的方式形成混合物。而且,该方法中使用的组分可以容易地回收和/或在其他过程中重复使用。

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