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METHOD FOR REMOVING OF COPPER-ION FROM SOLUTIONS CONTAINING LOW CONCENTRATION COPPER

机译:从低浓度铜溶液中去除铜离子的方法

摘要

The present invention relates to a method for removing copper ions, wherein the method includes: a step (a) of selectively absorbing and removing the copper ions from a mixed solution, which contains the copper ions and at least one or two metal ions selected from nickel ions, cobalt ions, and iron ions, using an ion exchange resin which is a chelate resin having an iminodiacetic acid functional group; and a step (b) of recovering copper by detaching the copper from the ion exchange resin in which the copper ions are absorbed. The present invention also relates to the copper which is detached and recovered from the ion exchange resin, which the copper ions are absorbed in, by the method using an eluent containing 2 to 12 vol% of sulfuric acid. [Reference numerals] (AA) Solution including nickel, cobalt, iron, and low concentration copper;(BB) Sulfuric acid/sodium hydroxide;(CC) pH adjustment;(DD) Copper attachment;(EE) Resin/solution separation;(FF) Ion exchange resin;(GG) Solution;(HH) Eluant;(II) Detachment;(JJ) Nickel/cobalt recovery process;(KK) Resin/eluant separation;(LL) Ion exchange resin;(MM) Copper-containing solution;(NN) Copper recovery process
机译:本发明涉及一种去除铜离子的方法,其中该方法包括:步骤(a):从混合溶液中选择性地吸收和去除铜离子,所述混合溶液包含铜离子和选自以下的至少一种或两种金属离子。使用作为具有亚氨基二乙酸官能团的螯合树脂的离子交换树脂,使用镍离子,钴离子和铁离子。步骤(b)是通过从吸收了铜离子的离子交换树脂中分离铜来回收铜的步骤。本发明还涉及通过使用含有2至12体积%的硫酸的洗脱液的方法从吸收了铜离子的离子交换树脂上分离和回收的铜。 [标号](AA)包括镍,钴,铁和低浓度铜的溶液;(BB)硫酸/氢氧化钠;(CC)pH调节;(DD)铜附着;(EE)树脂/溶液分离;( FF)离子交换树脂;(GG)溶液;(HH)洗脱液;(II)分离;(JJ)镍/钴回收工艺;(KK)树脂/洗脱液分离;(LL)离子交换树脂;(MM)铜-含溶液;(NN)铜回收工艺

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