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METHOD FOR SYNTHESIS OF MOLYBDENUM CARBIDE CATALYST FOR HYDRODEOXYGENATION

机译:合成加氢钼碳化物催化剂的方法

摘要

The present invention relates to a molybdenum carbide catalyst which is used in a process of manufacturing hydrocarbons, especially diesel class hydrocarbons, through hydrodeoxygenation reaction from bio-oil and fatty acid produced from the bio-oil; and to a manufacturing method thereof. The molybdenum carbide supported catalyst of the present invention is able to obtain hydrocarbons in high yield from organic oxygen compounds since molybdenum carbide nanoparticles with high dispersion rate are easily manufactured using supercritical fluid; is environmentally-friendly by preventing the emission of sulfur during hydrodeoxygenation reaction since sulfur compounds are not used like existing catalysts in order to maintain performance and activation processes of the catalysts as stated above; and is economical since hydrogen consumption due to water-soluble gas shift reaction or methanation reaction caused by the intense side reaction of an existing noble metal catalyst is able to be reduced. Additionally, the present invention manufactures renewable fuel without oxygen, thereby being able to solve problems caused by using existing FAME biodiesel in addition to an existing gasoline or diesel engine.
机译:碳化钼催化剂技术领域本发明涉及一种碳化钼催化剂,其用于通过由生物油和由生物油产生的脂肪酸的加氢脱氧反应来制造烃,特别是柴油级烃的方法。及其制造方法。本发明的负载碳化钼的催化剂能够从有机含氧化合物高收率地得到烃,这是因为使用超临界流体容易制造出分散速度高的碳化钼纳米粒子。通过防止加氢脱氧反应中硫的排放,对环境友好,因为不像现有催化剂那样使用硫化合物来保持如上所述的催化剂性能和活化过程;并且由于可以减少由于现有贵金属催化剂的强烈副反应引起的水溶性气体转移反应或甲烷化反应引起的氢消耗,因此是经济的。另外,本发明制造不含氧气的可再生燃料,从而能够解决除现有的汽油或柴油发动机之外还使用现有的FAME生物柴油引起的问题。

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