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A method for the analysis of isotope signatures and the mass analysis

机译:同位素特征分析和质量分析的方法

摘要

The method (100) in a mass analysis system (2) for the analysis of isotope signatures, wherein the mass analysis system (2) is a chromatography module (4), a ionization (10), a mass separation module the first stage (12), a collision cell module (14), a mass separation module second stage (16), a detector (18) and an electronic device (6) having a memory (8), andthe method comprising:Carrying out a first mass spectrometry process with the mass analysis system (2) andIt is being hauled in, (110) of a plurality of mass intensity values, which correspond to a plurality of masses, by means of the electronic device (6),Comparing (120) of the plurality of mass intensity values by means of the electronic device (6) with at least one criterion, in order to determine whether any mass of the plurality of masses is of interest, wherein said at least one criterion isotopic conditions and / or mass differences between isotopes the same compound, and wherein the criterion of the differences in mass a first difference in weight (220, 320) between a first mass (210, 212) and a second mass (230, 232), and a second difference in weight between the first mass (212) and a third mass (242), and wherein the criterion of isotopic conditions a first ratio (330) between an intensity of the first mass value (210, 211, 213) and an intensity of the second mass value (230, 231, 233) and a second ratio (360) between the intensity of the first mass value (213) and an intensity of a third mass value (243); and ..
机译:质量分析系统(2)中用于分析同位素特征的方法(100),其中质量分析系统(2)是色谱模块(4),电离(10),第一阶段的质量分离模块( 12),碰撞池模块(14),第二质量分离模块(16),检测器(18)和具有存储器(8)的电子设备(6),该方法包括:进行第一质谱分析用质量分析系统(2)进行处理,并通过电子设备(6)将其对应于多个质量的多个质量强度值(110)拖入(110)中。借助于电子设备(6)利用至少一个标准确定多个质量强度值,以便确定是否对多个质量中的任何一个质量感兴趣,其中所述至少一个标准同位素条件和/或之间的质量差同位素相同的化合物,并且其中质量差异的标准第一质量(210,212)和第二质量(230,232)之间的第一重量差(220,320),以及第一质量(212)和第三质量(242)之间的第二重量差,其中同位素标准以第一质量值(210、211、213)的强度与第二质量值(230、231、233)的强度之间的第一比率(330)和第二比率(360)为条件在第一质量值的强度(213)和第三质量值的强度(243)之间;和..

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