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Single crystal CVD synthetic diamond material .

机译:单晶CVD合成金刚石材料。

摘要

A single crystal CVD synthetic diamond material has a total concentration of nitrogen as grown above 5ppm, and a uniform distribution of the defect, the uniform distribution of defects, the following features of defined by one or two or more, the feature is as follows, namely, (i) the total nitrogen concentration, secondary ion mass over an area of ??more than 50 50?m using the following analysis region 10?m Once mapped by analysis (SIMS), the mean having a point-to-point variations in less than 30% of the total nitrogen concentration value, or it is mapped by SIMS over an area of ??more than 200 200?m by using the following analysis region 60?m that the, to have a point-to-point variations in less than 30% of the average total nitrogen concentration value, measured using and (ii) the nitrogen vacancy defects remain grown (NV) concentration 77K UV visible absorption measurement The is 50ppb or Te, nitrogen vacancy defects, the area of ??more than 50 50?m data interval is excited, and less than 10?m using a 514nm laser excitation source of 10?m or less spot size at room temperature using a 50mW continuous wave laser over and is mapped, uniformly distributed in synthetic single crystal CVD diamond material so that low-point-to-point variations occur, of nitrogen vacancies photoluminescence peak of the high photoluminescence intensity of region and the low photoluminescence intensity of area intensity area ratio, 575nm photoluminescence peak (NV 0 ) or 637nm photoluminescence peak (NV -.... ) for Kano any two be less than times, the variation of (iii) Raman intensity, using a 50mW continuous wave laser is excited using 514nm laser excitation source of 10?m or less spot size at room temperature (as a result, the Raman peak at 552.4nm Raman occurs), and the mapped over an area of ??more than 50 50?m data interval of less than 10?m, it is intended as a low point-to-point variations occur, the low Raman intensity of the region and the high Raman intensity regions that the ratio of the peak area is less than 1.25, is 50ppb or more measured using and (iv) the nitrogen vacancy defects remain grown (NV) concentration 77K UV visible absorption measurement, 50mW when excited using 514nm laser excitation source below the spot size 10?m at 77K using a continuous wave laser, a 120-fold of the Raman intensity at 552.4nm NV. 0. 200 times greater than NV Raman intensity at intensity and / or 552.4nm at 575nm corresponding to. -. The intensity at 637nm corresponding to the given, (v) a single substitutional nitrogen defects (N. S. ) Concentration is is 5ppm or more, a single substitutional nitrogen defects, 1344cm . -1. 0.5mm along with the use of the infrared absorption features. 2. Of by sampling a larger area than the area, to be uniformly distributed in the synthetic single crystal CVD diamond material as the variation is less than 80% derived by dividing the standard deviation by the average value, (vi ) the variation of the red luminescence intensity obtained by the standard deviation divided by the average value is less than 15%, (vii) the average standard deviation of the neutral single substitutional nitrogen concentration is less than 80%, (viii) There the intensity of color was measured using a histogram from the microscope image including the average gray value of greater than 50, color intensity, the variation of gray less than 40% characterized by the gray value standard deviation divided by the gray value average Single crystal CVD synthetic diamond material which is characterized in that as is it is that it is uniform in the single crystal CVD synthetic diamond material. .. [Selection Figure Figure 3.
机译:单晶CVD合成金刚石材料的总氮浓度超过5ppm时,缺陷的均匀分布,缺陷的均匀分布,以下的特征由1个或2个以上定义,特征如下:即,(i)总氮浓度,使用以下分析区域,在大于5050μm的区域上的二次离子质量:10μm一旦通过分析(SIMS)进行映射,则平均值具有点对点小于总氮浓度值的30%的变化,或者通过SIMS使用以下分析区域60?m将其映射到200200?m以上的区域,点偏差小于平均总氮浓度值的30%,使用和(ii)保持氮空位缺陷的生长(NV)浓度77K UV可见吸收测量值是50ppb或Te,氮空位缺陷的面积为?超过50 50?m的数据间隔被激发,在室温下使用50mW连续波激光在10nm或更小的点尺寸的514nm激光激发源中,发现小于10μm的光,并将其均匀地分布在合成单晶CVD金刚石材料中,以便从低点区域的高光致发光强度和面积强度/面积比的低光致发光强度的氮空位光致发光峰出现点变化,分别为575nm光致发光峰(NV 0 )或637nm光致发光峰(NV -.... )对于任何两个Kano小于倍,(iii)拉曼强度的变化,使用50mW连续波激光器,使用10nm或更小的光斑大小的514nm激光激发源进行激发在室温下(结果,在552.4nm拉曼峰出现拉曼峰),并将其映射到面积大于50×50μm且小于10μm的数据区域,它打算作为低点-发生点变化,该区域的拉曼强度较低,而拉玛强度较高n个峰面积比小于1.25的强度区域,使用以下方法测量为50ppb或更高:(iv)保持氮空位缺陷生长(NV)浓度77K UV可见吸收测量,使用以下514nm激光激发源激发时为50mW使用连续波激光在77K时光斑尺寸为10?m,是552.4nm NV处拉曼强度的120倍。 0。大于NV拉曼强度在强度上的200倍和/或在575nm处的552.4nm对应。 - 与给定值对应的637nm处的强度,(v)单个替代氮缺陷(N. S. )浓度为5ppm或更高,单个替代氮缺陷为1344cm。 -1。 0.5mm以及使用红外吸收功能。 2. 其中,通过将标准偏差除以平均值得出的变化小于80%,通过对比该区域更大的区域进行采样,使其均匀地分布在合成单晶CVD金刚石材料中, (vi)通过标准偏差除以平均值获得的红色发光强度变化小于15%,(vii)中性单取代氮浓度的平均标准偏差小于80%,(viii)使用直方图从显微镜图像测量颜色强度,包括大于50的平均灰度值,颜色强度,小于40%的灰度变化(其特征在于灰度值标准偏差除以灰度值平均值)。合成金刚石材料,其特征在于它在单晶CVD合成金刚石材料中是均匀的。 .. [选择图3。

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