首页> 外国专利> It comprises a Group VIII and Group VIB metals, and has a acetic acid and C1-C4 dialkyl succinate, available catalysts and are prepared in the hydrogenation process.

It comprises a Group VIII and Group VIB metals, and has a acetic acid and C1-C4 dialkyl succinate, available catalysts and are prepared in the hydrogenation process.

机译:它包含VIII族和VIB族金属,并具有乙酸和琥珀酸C1-C4二烷基酯(可使用的催化剂),并且在氢化过程中制备。

摘要

A catalyst may be used in the hydrogenation treatment method, the amorphous support based on alumina, phosphorus, and C1-C4 dialkyl succinate, acetate, the invention, at least one group VIII includes at least one element, preferably, and a hydrogenation dehydrogenation group comprising cobalt and molybdenum, the Raman spectrum of the catalyst hair Gin heteropolyanion (990cm -1 and / or 974) of the group VIB element and , and C1-C4 dialkyl succinate, and including the strongest band is characteristic of acetic acid (896cm -1), relates to a catalyst. Preferably, dialkyl succinate used is a dimethyl succinate, the main band is a 853cm -1. The present invention also provides a method of preparing the catalyst, the catalyst precursor, the elements, in particular, molybdenum Group VIB and Group VIII - includes a pair of cobalt, and phosphorus, which are introduced by impregnation , then allowed to dry at 180 ℃ temperatures below was impregnated with (if this object is not introduced completely already pre) Phosphorus compound dialkyl succinate and acetate, then, after maturation, 180 ℃ allowed to dry to a lower temperature, is then sulfurized in some cases, to a method. The present invention relates to the use of the catalyst in the hydrogenation process in any manner.
机译:在氢化处理方法中可以使用催化剂,基于氧化铝,磷和C 1 -C 4的琥珀酸二烷基酯的无定形载体,乙酸盐,本发明中,至少第VIII族优选包含至少一种元素,以及氢化脱氢基团。包含钴和钼,VIB元素的催化剂毛杜松子酒杂多阴离子(990cm -1 和/或974)的拉曼光谱,以及C1-C4琥珀酸二烷基酯,并且其中最强的谱带为乙酸(896cm -1)的特征,涉及一种催化剂。优选地,所用的琥珀酸二烷基酯是琥珀酸二甲酯,主带是853cm -1。本发明还提供了一种制备催化剂,催化剂前体,元素,特别是钼族的方法。 VIB和VIII族-包括一对钴和磷,它们是通过浸渍引入的,然后在180℃以下的温度下干燥,并用(如果尚未完全引入该物体进行预浸渍)磷化合物琥珀酸二烷基酯和乙酸盐,然后,在成熟后,允许180℃干燥至更低的温度,然后在某些情况下被硫化,成为一种方法。本发明涉及催化剂以任何方式在氢化过程中的用途。

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