首页> 外国专利> SOLID ELECTROLYTE WITH HIGH ION-CONDUCTIVITY AND METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMICAL SYSTEM USING SOLID ELECTROLYTE

SOLID ELECTROLYTE WITH HIGH ION-CONDUCTIVITY AND METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMICAL SYSTEM USING SOLID ELECTROLYTE

机译:具有高离子电导率的固体电解质及其制造方法以及使用该固体电解质的电化学系统

摘要

An object thereof according to the present invention is to provide a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity even in an alkaline form, and also can stably keep high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state; a method for manufacturing the same; and an electrochemical system using the solid electrolyte, such as a fuel cell. The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, as constituents, and also contains a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a raw material solution in which a solvent including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.
机译:本发明的目的是提供一种离子传导率高的固体电解质,该电解质便宜且即使在碱性状态下也具有高传导率,并且由于化合物的少量泄漏也可以稳定地保持高传导率。即使在潮湿状态下也具有导电性;一种制造方法;以及使用固体电解质的电化学系统,例如燃料电池。具有高离子导电性的固体电解质包含至少包含聚乙烯醇和锆酸化合物作为成分的杂化化合物,并且还包含具有胺,季铵化合物和/或亚胺结构的含氮有机化合物,通过在原料溶液中水解锆盐或氧锆盐而获得,该原料溶液中的溶剂包括水,聚乙烯醇,锆盐或氧锆盐以及具有胺,季铵化合物和/的结构的含氮有机化合物或亚胺共存,除去溶剂并与碱接触。

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