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SOLID ELECTROLYTE WITH HIGH ION-CONDUCTIVITY AND METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMICAL SYSTEM USING SOLID ELECTROLYTE
SOLID ELECTROLYTE WITH HIGH ION-CONDUCTIVITY AND METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMICAL SYSTEM USING SOLID ELECTROLYTE
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机译:具有高离子电导率的固体电解质及其制造方法以及使用该固体电解质的电化学系统
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摘要
An object thereof according to the present invention is to provide a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity even in an alkaline form, and also can stably keep high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state; a method for manufacturing the same; and an electrochemical system using the solid electrolyte, such as a fuel cell. The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, as constituents, and also contains a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a raw material solution in which a solvent including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.
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