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Organic solar cell of the bulk heterojunction type comprising an imide based conjugated backbone compound as photoactive material

机译:本体异质结型有机太阳能电池,其包含基于酰亚胺的共轭骨架化合物作为光敏材料

摘要

The invention relates to a solar cell comprising at least a substrate (10), a cathode (11), a hole conductive layer (12), a bulk heterojunction photoactive layer (13) of a blend of a donor material and an acceptor material, an electron conductive layer (14) and an anode (15), wherein the blend comprises at least one photoactive material comprising a conjugated backbone system having: i) the general formula R2-imide-Ar-L-Ar-imide-R3, wherein Ar-L-Ar is a conjugated chromophore, imide is imide -OCNCO-, R2 and R3 are organic groups, bonded to the N atom of the respective imide and forming a conjugated bond with the respective imide; or. ii) repeating units (R4-imide-Ar-L-Ar-imide)n, wherein Ar-L-Ar is a conjugated chromophore, imide is imide -OCNCO-, R4 is an organic group bonded to the N atom of the respective imide and forming a conjugated bond with the respective imide and n is the number of repeating units.
机译:本发明涉及一种太阳能电池,其至少包括衬底(10),阴极(11),空穴传导层(12),由施主材料和受主材料的混合物构成的本体异质结光敏层(13),电子传导层(14)和阳极(15),其中共混物包含至少一种光敏材料,该材料包含共轭主链系统,该共轭主链系统具有:i)通式R2-酰亚胺-Ar-L-Ar-酰亚胺-R3,其中Ar-L-Ar是共轭生色团,酰亚胺是酰亚胺-OCNCO-,R 2和R 3是有机基团,键合到各自酰亚胺的N原子上并与各自的酰亚胺形成共轭键。要么。 ii)重复单元(R 4-酰亚胺-Ar-L-Ar-酰亚胺)n,其中Ar-L-Ar是共轭发色团,酰亚胺是酰亚胺-OCNCO-,R 4是结合到各自N原子上的有机基团酰亚胺并与各自的酰亚胺形成共轭键,n为重复单元数。

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