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POWER-TYPE NICKEL COBALT LITHIUM MANGANESE OXIDE MATERIAL, AND PREPARATION METHOD THEREFOR AND USES THEREOF

机译:动力型镍钴锰酸锂材料及其制备方法和用途

摘要

The present invention relates to the technical field of preparation of a nickel cobalt lithium manganese oxide positive electrode material. Disclosed are a power-type nickel cobalt lithium manganese oxide material and a preparation method therefor and uses thereof. The preparation method comprises: adding an organic acid into a mixed aqueous solution of a lithium source, a nickel source, a cobalt source and a manganese source, aging, obtaining a sol precursor, obtaining a gel fiber through electrospinning, and obtaining the power-type nickel cobalt lithium manganese oxide material after calcination. In the present invention, the nickel cobalt lithium manganese oxide material of a nano-fiber structure is prepared by using a sol-gel electrospinning method, and the nickel cobalt lithium manganese oxide material of a nano-fiber structure has a uniform structure size, thereby effectively reducing surface energy, and improving a capacity of lithium ions. In addition, the nano-fiber structure can reduce impedance of lithium ion diffusion in an intercalation and deintercalation process, thereby enabling the lithium ions to diffuse fast. Meanwhile, the material has a larger surface area and more reaction active sites, and can provide a higher specific capacity. The method of the present invention has a simple process, can implement the electrospinning without adding a polymeric reagent, reduce cost of using a polymer, and reduce the impact of the polymer on a nano-structure.
机译:本发明涉及镍钴锂锰氧化物正极材料的制备技术领域。本发明公开了一种动力型镍钴锂锰氧化物材料及其制备方法和用途。制备方法包括:将有机酸添加到锂源,镍源,钴源和锰源的混合水溶液中,陈化,获得溶胶前体,通过电纺获得凝胶纤维,并获得功率-型镍钴锂锰氧化物煅烧后的材料。在本发明中,通过使用溶胶-凝胶电纺丝法制备纳米纤维结构的镍钴锂锰氧化物材料,并且纳米纤维结构的镍钴锂锰氧化物材料具有均匀的结构尺寸,从而有效降低表面能,提高锂离子容量。另外,纳米纤维结构可以在嵌入和脱嵌过程中降低锂离子扩散的阻抗,从而使锂离子快速扩散。同时,该材料具有更大的表面积和更多的反应活性部位,并且可以提供更高的比容量。本发明的方法具有简单的工艺,可以在不添加聚合物试剂的情况下进行静电纺丝,降低了使用聚合物的成本,并减少了聚合物对纳米结构的影响。

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