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COMPOSITION BASED ON ZIRCONIUM OXIDE AND AT LEAST ONE RARE EARTH OXIDE DIFFERENT FROM CERIUM, WITH SPECIFIC POROSITY, WAYS OF ITS PRODUCTION AND ITS APPLICATION IN CATALYSTS
COMPOSITION BASED ON ZIRCONIUM OXIDE AND AT LEAST ONE RARE EARTH OXIDE DIFFERENT FROM CERIUM, WITH SPECIFIC POROSITY, WAYS OF ITS PRODUCTION AND ITS APPLICATION IN CATALYSTS
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机译:基于氧化锆和铈的至少一种稀土氧化物的组合物,具有特定的孔隙率,其生产方式及其在催化剂中的应用
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摘要
1. A composition based on zirconium oxide and at least one rare earth oxide other than cerium, with a mass fraction of zirconium oxide of at least 50%, characterized in that after calcining at a temperature of 900 ° C for 4 hours, there are two sets of pores, the corresponding diameters of which are grouped for the first set near a value from 20 nm to 40 nm and for the second set about a value from 80 nm to 200 nm. 2. The composition according to claim 1, characterized in that the diameter of the first pore population is grouped around a value from 20 nm to 35 nm and more specifically from 20 nm to 30 nm, and the diameter of the second pore population is grouped around a value from 80 nm to 150 nm and more specifically from 90 nm to 110 nm. 3. A composition according to claim 1 or 2, characterized in that, after calcining at a temperature of 900 ° C for 4 hours, it has a total pore volume of at least 1.3 ml Hg / g, more specifically at least 1.5 ml Hg / g. 4. A composition according to claim 1 or 2, characterized in that, after calcining at 1100 ° C for 4 hours, a set of pores is observed in it, the diameter of which is grouped around a value from 30 nm to 70 nm. A composition according to claim 1 or 2, characterized in that, after calcining at 1100 ° C for 4 hours, it has a total pore volume of at least 0.9 ml Hg / g. 6. A composition according to claim 1 or 2, characterized in that it is based on the oxides of at least two rare earth elements other than cerium. A composition according to claim 1 or 2, characterized in that it has a content of rare earth oxide other than cerium from 10% to 30% .8. A composition according to claim 1 or 2, characterized in that the rare-earth element (s) other than cerium is (are) selected from the group consisting of
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