首页> 外国专利> COMPOSITION BASED ON ZIRCONIUM OXIDE AND AT LEAST ONE RARE EARTH OXIDE DIFFERENT FROM CERIUM, WITH SPECIFIC POROSITY, WAYS OF ITS PRODUCTION AND ITS APPLICATION IN CATALYSTS

COMPOSITION BASED ON ZIRCONIUM OXIDE AND AT LEAST ONE RARE EARTH OXIDE DIFFERENT FROM CERIUM, WITH SPECIFIC POROSITY, WAYS OF ITS PRODUCTION AND ITS APPLICATION IN CATALYSTS

机译:基于氧化锆和铈的至少一种稀土氧化物的组合物,具有特定的孔隙率,其生产方式及其在催化剂中的应用

摘要

1. A composition based on zirconium oxide and at least one rare earth oxide other than cerium, with a mass fraction of zirconium oxide of at least 50%, characterized in that after calcining at a temperature of 900 ° C for 4 hours, there are two sets of pores, the corresponding diameters of which are grouped for the first set near a value from 20 nm to 40 nm and for the second set about a value from 80 nm to 200 nm. 2. The composition according to claim 1, characterized in that the diameter of the first pore population is grouped around a value from 20 nm to 35 nm and more specifically from 20 nm to 30 nm, and the diameter of the second pore population is grouped around a value from 80 nm to 150 nm and more specifically from 90 nm to 110 nm. 3. A composition according to claim 1 or 2, characterized in that, after calcining at a temperature of 900 ° C for 4 hours, it has a total pore volume of at least 1.3 ml Hg / g, more specifically at least 1.5 ml Hg / g. 4. A composition according to claim 1 or 2, characterized in that, after calcining at 1100 ° C for 4 hours, a set of pores is observed in it, the diameter of which is grouped around a value from 30 nm to 70 nm. A composition according to claim 1 or 2, characterized in that, after calcining at 1100 ° C for 4 hours, it has a total pore volume of at least 0.9 ml Hg / g. 6. A composition according to claim 1 or 2, characterized in that it is based on the oxides of at least two rare earth elements other than cerium. A composition according to claim 1 or 2, characterized in that it has a content of rare earth oxide other than cerium from 10% to 30% .8. A composition according to claim 1 or 2, characterized in that the rare-earth element (s) other than cerium is (are) selected from the group consisting of
机译:1.基于氧化锆和至少一种除铈以外的稀土氧化物的组合物,其氧化锆的质量分数至少为50%,其特征在于,在900℃的温度下煅烧4小时后,存在两组孔的直径相对应,第一组接近20 nm至40 nm,第二组约为80 nm至200 nm。 2.根据权利要求1所述的组合物,其特征在于,所述第一孔群的直径被分组为约20nm至35nm,更具体地为20nm至30nm,并且所述第二孔群的直径被分组。大约在80 nm至150 nm的范围内,更具体地在90 nm至110 nm的范围内。 3.根据权利要求1或2的组合物,其特征在于,在900℃的温度下煅烧4小时后,其总孔体积至少为1.3ml Hg / g,更具体地至少为1.5ml Hg。 / G。 4.根据权利要求1或2所述的组合物,其特征在于,在1100℃下煅烧4小时后,在其中观察到一组孔,其直径分组在30nm至70nm的值附近。 3.根据权利要求1或2所述的组合物,其特征在于,在1100℃下煅烧4小时后,其总孔体积为至少0.9ml Hg / g。 6.根据权利要求1或2的组合物,其特征在于它基于至少两种除铈以外的稀土元素的氧化物。 3.根据权利要求1或2所述的组合物,其特征在于,除了铈以外,稀土氧化物的含量为10%至30%.8。 3.根据权利要求1或2所述的组合物,其特征在于,除铈以外的稀土元素选自由以下组成的组:

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