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Dispersant for suspension polymerization of vinyl chloride resin and PROCESS FOR ITS PREPARATION

机译:氯乙烯树脂悬浮聚合用分散剂及其制备方法

摘要

1. A dispersant for suspension polymerization, comprising modified polyvinyl alcohol having a component unit represented by the following chemical formula (A), and characterized by a saponification value of 75% (mol.) Or more and less than 90% (mol.) , absorbance in the wavelength region of 280 nm, as defined for the water or mixed water and methanol solution at a concentration of 0.2% (wt.) in the range from 0.5 to 2.5, and a viscosity, as determined by indicated in the document JIS K 6726, component 4 mPas or more and less than 30 mPas s.gde Hee Hmogut be identical to each other or different from each other and represent an alkyl group, characterized by the number of carbon atoms ranging from 1 to 12, a hydrogen atom or metal, g is an integer ranging from 1 to 3.2. A dispersant for suspension polymerization according to Claim. 1, characterized by an optical density in the wavelength region of 325 nm, by definition at 20 ° C for water or mixed water and methanol solution at a concentration of 0.2% (wt.) In the range of from 0.02 to 0,20.3. A dispersant for suspension polymerization according to Claim. 1 or 2, characterized by a cloud point as defined for the aqueous solution at a concentration of 4% (wt.) Of 50 ° C and bolee.4. Vinyl chloride resin having a bulk specific density was 0.05 g / cc more, and the resultant dispersion in water of the vinyl chloride monomer or a monomer mixture containing vinyl chloride monomer, by using a dispersant for suspension polymerization according to any one of claims. 1-3
机译:1.一种用于悬浮聚合的分散剂,其包含具有以下化学式(A)表示的组成单元的改性聚乙烯醇,其特征在于皂化值为75%(摩尔)以上且小于90%(摩尔)。如在文件中指出的那样,在浓度为0.5%至2.5%的水或混合的水和甲醇溶液中浓度为0.2%(重量)的280 nm波长区域的吸光度和粘度JIS K 6726,组分4 mPas以上且小于30 mPas s.gde Hee Hmogut彼此相同或彼此不同,代表烷基,特征在于碳原子数为1至12,氢原子或金属,g为1到3.2的整数。根据权利要求1的用于悬浮聚合的分散剂。在图1中,其特征在于,在20℃下,对于水或混合水和甲醇溶液的浓度为0.2%(重量),在325nm的波长范围内的光密度为0.02至0.20.3。根据权利要求1的用于悬浮聚合的分散剂。 1或2,其特征在于在50℃和沸腾的浓度为4%(重量)的水溶液中定义的浊点。4。松散比重为0.05g / cc以上的氯乙烯树脂,通过使用根据权利要求1至13中任一项所述的悬浮聚合用分散剂,将所得氯乙烯单体或含有氯乙烯单体的单体混合物分散在水中。 1-3

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