首页> 外国专利> Cis-4-(benzod 1',3'-dioxol-5'-yl)-5-(1-iodoethyl)-dihydrofuran-2-one and trans-4-(benzod1',3'-dioxol-5'-yl)-5-(1-iodoethyl)-dihydrofuran-2-one and a method for their simultaneous obtaining

Cis-4-(benzod 1',3'-dioxol-5'-yl)-5-(1-iodoethyl)-dihydrofuran-2-one and trans-4-(benzod1',3'-dioxol-5'-yl)-5-(1-iodoethyl)-dihydrofuran-2-one and a method for their simultaneous obtaining

机译:顺式-4-(苯并[d] [1',3']-二氧杂-5'-基)-5-(1-碘乙基)-二氢呋喃-2-酮和反式4-(苯并[d] [1 ',3']-二恶唑-5'-基)-5-(1-碘乙基)-二氢呋喃-2-酮及其同时获得的方法

摘要

the invention relates to racemicznych? - jodo -? - lactone ring of 1,3 - benzodioksolowym model 1 and 2 shown in figure and the way their simultaneous receive.method of simultaneously receiving racemicznych? - jodo -? - lactone ring of 1,3 - benzodioksolowym is that (e) - 4 - (benzo [d] [1 ', 3') dioksol - 5 '- yl) - shoe - 3 - en - 2 - he shall be carried out by czteroetapowej synthesis in jodolaktonu00f3w mixture which then is excreted in the form of pure by column chromatography with cis - 4 - (benzo [d] [1 ',3 '] - dioksol - 5' - yl) - 5 - (1 - jodoetylo) - dihydrofuran-2 - he and trans - 4 - (benzo [d] [1 ', 3') - dioksol - 5 '- yl) - 5 - (1 - jodoetylo) - dihydrofuran-2 - he. both received lactones may find application in the food industry.lactone of formula 1 can be used as a constituent of preparations to combat fitopatogennych filamentous fungi of the fusarium and lactone of formula 2 can be used to protect crops and cereal storage before insect pests.
机译:发明涉及消旋体? -柔道-? -1,3的内酯环-图1和图2所示的benzodioksolowym模型以及它们同时接收的方式。 -柔道-? -1,3的内酯环-苯并二oksolowym是(e)-4-(苯并[d] [1',3')二oksol-5'-yl)-鞋-3-en-2-应进行通过czteroetapowej在jodolakton u00f3w混合物中合成,然后用顺式-4-(苯并[d] [1',3']-二醇-5'-酰基)-5-(1 -jodoetylo)-dihydrofuran-2-他和反式-4-(苯并[d] [1',3')-dioksol-5'-yl)-5-(1-jodoetylo)-dihydrofuran-2-he。式1的内酯可以用作抗镰刀菌的致病性丝状真菌的制剂的成分,式2的内酯可以用于在虫害之前保护农作物和谷物的储存。

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