首页> 外国专利> SELECTIVE EXTRACTION AND CONVERSION OF A CELLULOSIC FEEDSTOCK TO ETHYLENE GLYCOL

SELECTIVE EXTRACTION AND CONVERSION OF A CELLULOSIC FEEDSTOCK TO ETHYLENE GLYCOL

机译:纤维素原料的选择性萃取和转化为乙二醇

摘要

The present invention relates to a process for selectively solubilizing and removing lignin and hemi-cellulose components of cellulosic biomass and obtaining a cellulosic feedstock having a higher proportion of cellulose, as compared to the biomass from which it is derived, and having a greater cellulose Crystallinity Index. In particular, the process comprises: i) contacting cellulosic biomass with a deep eutectic solvent (DES) formed from a mixture of a) a choline derivative selected from choline chloride, chlorocholine chloride, choline acetate, acetylcholine chloride or phosphatidyl choline; and b) an alpha-hydroxy carboxylic acid;and ii) obtaining a solid cellulosic feedstock which has a higher proportion of cellulose component, as compared with the cellulosic biomass from step i), wherein the majority of the cellulosic feedstock obtained in step ii) is obtained without regenerating cellulose by precipitation.
机译:本发明涉及一种选择性地增溶和除去纤维素生物质的木质素和半纤维素组分并获得与衍生自其的生物质相比具有更高比例的纤维素并且具有更大的纤维素结晶度的纤维素原料的方法。指数。特别地,该方法包括:i)使纤维素生物质与由以下混合物形成的深共熔溶剂(DES)接触:a)选自氯化胆碱,氯化胆碱,乙酸胆​​碱,乙酰胆碱氯化物或磷脂酰胆碱的胆碱衍生物; (b)α)-羟基羧酸;和(b)α-羟基羧酸;和(ii)获得与来自步骤(i)的纤维素生物质相比具有更高比例的纤维素成分的固体纤维素给料,其中,步骤ii)中获得的大部分纤维素给料得到的产物无需通过沉淀使纤维素再生。

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