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PRODUCTION OF HIGH QUALITY DIESEL FUEL AND LUBRICANT FROM HIGH BOILING AROMATIC CARBONACEOUS MATERIAL

机译:用高沸点芳族碳质材料生产高质量的柴油燃料和润滑剂

摘要

A broad embodiment of the present disclosure relates to a process for removal of at least 20%, 40% or 80% of the aromatics content of the fraction boiling above 190°C from a heavy hydrocarbonaceous feedstock comprising at least 30wt% aromatics, at least 3000 wt ppm nitrogen and at least 0.5wt% oxygen said method being carried out in a single stage in which no intermediate stream is withdrawn and comprising the steps of a. providing a hydrotreater feed by combining said heavy hydrocarbonaceous feedstock with excess hydrogen, providing a hydrotreater feed, b. providing a hydrotreated hydrocarbon product comprising less than 30 wt ppm nitrogen, less than 20 wt ppm nitrogen or less than 10 wt ppm nitrogen by hydrotreating said hydrotreater feed by contacting it with a material catalytically active in hydrotreatment under hydrotreatment conditions, c. providing a hydrotreated product either as the hydrotreated hydrocarbon product of step b or by fractionation as a fraction of said hydrotreated hydrocarbon product, with the associated benefit of a process providing a low level of nitrogen in the hydrocarbon product also providing a high potential for dearomatization. The aromatics content of the heavy hydrocarbonaceous feedstock may typically be between 30wt% aromatics and 90wt% aromatics. The nitrogen content of the heavy hydrocarbonaceous feedstock may typically be between 3000 wt ppm and10000 wt ppm. The oxygen content of the heavy hydrocarbonaceous feedstock may typically be between 0.5wt% and 10 wt%. The removal of aromatics content from the fraction boiling above 190°C may be from 20%, 40% or 80% to 99%or 100%.
机译:本公开的广泛的实施方案涉及一种从包含至少30wt%的芳族化合物,至少30wt%的芳族化合物的重质烃原料中除去沸点在190℃以上的馏分的至少20%,40%或80%的芳族化合物含量的方法。 3000重量ppm的氮气和至少0.5重量%的氧气,所述方法在不抽出任何中间物流的单一阶段中进行,并且包括以下步骤。通过将所述重质烃原料与过量的氢气混合来提供加氢处理剂进料,从而提供加氢处理剂进料,b。通过使所述加氢处理剂进料与在加氢处理条件下在加氢处理中具有催化活性的物质接触来加氢处理所述加氢处理剂进料,从而提供包含少于30重量ppm的氮,少于20重量ppm的氮或少于10重量ppm的氮的加氢处理的烃产物,c。提供作为步骤b的加氢处理的烃产物或通过分馏作为所述加氢处理的烃产物的馏分的加氢处理的产物,该方法的相关益处是在烃产物中提供低水平的氮,也提供了脱芳烃的高潜力。重质烃原料的芳族化合物含量通常可以在30wt%的芳族化合物和90wt%的芳族化合物之间。重质烃原料的氮含量通常可以在3000重量ppm至10000重量ppm之间。重质烃原料的氧含量通常可以在0.5重量%至10重量%之间。从沸点高于190℃的馏分中除去的芳族化合物含量可以为20%,40%或80%至99%或100%。

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