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NEW MATERIALS AND METHODS FOR DISPERSION OF NANOPARTICLES IN MATRICES WITH HIGH QUANTUM QUANTITIES AND STABILITY

机译:高量子量和稳定性矩阵中分散纳米粒子的新材料和方法

摘要

1. A method of producing a solid polymer with luminescent nanoparticles embedded in the polymer, comprising the following process steps: (1) mixing (i) luminescent nanoparticles having an outer surface coated with protective molecules containing a first functional group and a second functional group, and (ii) a precursor solid polymer, and (2) enabling the formation of a solid polymer, so that a solid polymer with embedded nanoparticles is obtained; in which the first functional group is formed so that interact with the outer surface of the quantum dot, and the second functional group has one or more functions selected from the group consisting of (a) miscibility with the solid polymer precursor and (b) the ability to react with the solid polymer precursor, where the protective molecules include two types protective molecules, where the first functional group of the first type of protective molecules contains a metal ion having coordination functionality and where the first functional group of the second type of protective molecules has the function alnost base Lyuisa.2. The method according to claim 1, in which the molar ratio of the protective molecules of the first type and the protective molecules of the second type is in the range of 0.8-1.2.3. The method according to any one of claims. 1 and 2, in which the second functional group of protective molecules of the first type and the second functional group of protective molecules of the second type are the same. 4. The method according to any one of paragraphs. 1 and 2, in which the solid polymer precursor contains monomers that are capable of forming the polymer as a result of the polymerization reaction. The method according to any one of paragraphs. 1-2, in which the precursor solid polymer
机译:1。一种制备具有嵌入聚合物中的发光纳米颗粒的固体聚合物的方法,其包括以下工艺步骤:(1)混合(i)具有涂覆有包含第一官能团和第二官能团的保护性分子的外表面的发光纳米颗粒。 (ii)前体固体聚合物,和(2)能够形成固体聚合物,从而获得具有嵌入的纳米颗粒的固体聚合物;其中形成第一官能团以与量子点的外表面相互作用,并且第二官能团具有一个或多个选自以下的官能团:(a)与固体聚合物前体的可混溶性和(b)与固体聚合物前体反应的能力,其中保护分子包括两种类型的保护分子,其中第一类型保护分子的第一官能团包含具有配位官能团的金属离子,并且其中第二类型保护分子的第一官能团分子具有基于神经碱Lyuisa的功能。2。 2.根据权利要求1所述的方法,其中,所述第一类型的保护分子与所述第二类型的保护分子的摩尔比在0.8-1.2.3的范围内。 11.根据权利要求1至10中任一项所述的方法。参照图1和图2,其中第一类型的保护分子的第二官能团和第二类型的保护分子的第二官能团相同。 4.根据段落中任一项的方法。参照图1和2,其中固体聚合物前体包含能够通过聚合反应形成聚合物的单体。根据段落中任一项的方法。 1-2,其中前体为固体聚合物

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