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METHOD OF IMPROVING FLOW PROPERTIES OF POLYMER MELTS
METHOD OF IMPROVING FLOW PROPERTIES OF POLYMER MELTS
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机译:改善聚合物熔体流动性的方法
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摘要
FIELD: chemistry.;SUBSTANCE: invention relates to a method of improving flow properties of a melt comprising a thermoplastic polymer, which includes adding to a composition of said thermoplastic polymer before or during treatment of the melt 0.005-0.5 wt %, relative to the weight of the thermoplastic polymer, of one or more comb copolymers or comb block copolymers which are obtained at a first step a) by free-radical polymerisation of an alkyl ester of acrylic or methacrylic acid with 1-10 carbon atoms in the alkyl group and, optionally, one or more monomers without an ester bond, and at a second step b) by modification in a polymer analogous transesterification reaction with a primary or secondary alcohol to form a comb or comb block copolymer. The object of the invention is also the use of said comb copolymers or comb block copolymers to improve flow properties of a melt comprising a thermoplastic polymer.;EFFECT: obtained comb copolymers or comb block copolymers reduce power consumption required for processing thereof, and reduce the risk of abruptions in the melt at high shearing rates.;13 cl, 15 tbl, 39 ex
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机译:技术领域本发明涉及一种改善包含热塑性聚合物的熔体的流动性能的方法,该方法包括在所述熔体处理之前或期间向所述热塑性聚合物的组合物中添加相对于所述热塑性聚合物0.005-0.5重量%。热塑性聚合物的重量,在第一步a)中通过丙烯酸或甲基丙烯酸烷基酯与烷基中1-10个碳原子的自由基聚合得到的一种或多种梳状共聚物或梳状嵌段共聚物,以及任选地,一种或多种不具有酯键的单体,并且在第二步骤b)中,通过在聚合物中与伯或仲醇的类似酯交换反应的改性来形成梳或梳状嵌段共聚物。本发明的目的还在于所述梳状共聚物或梳状嵌段共聚物用于改善包含热塑性聚合物的熔体的流动性能的用途。效果:获得的梳状共聚物或梳状嵌段共聚物降低了其加工所需的功耗,并降低了高剪切速率下熔体破裂的风险。; 13 cl,15 tbl,39 ex
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