首页> 外国专利> EXTRACTION AGENT FOR PRECIOUS METALS AND RHENIUM, AND EXTRACTION METHOD FOR PRECIOUS METALS AND RHENIUM USING SAME

EXTRACTION AGENT FOR PRECIOUS METALS AND RHENIUM, AND EXTRACTION METHOD FOR PRECIOUS METALS AND RHENIUM USING SAME

机译:贵金属和HEN的萃取剂及使用相同的贵金属和R的萃取方法

摘要

The present invention extracts precious metals from an acidic solution containing precious metals in an early and highly efficient manner. Provided is an extraction agent for precious metals that is represented by the general formula below. In the formula, R1 and R2 each represent the same alkyl group or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a discretionary group that is not an amino group and that bonds to ± carbon as an amino acid. It is preferable that the general formula have a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By subjecting an acidic solution containing precious metals to solvent extraction using the extraction agent for precious metals, a plurality of precious metals can be recovered all at once from a solution containing a large amount of various impurities. When recovering precious metals, it is preferable that the pH be set to 3.0 or less and further preferable that the pH be set to 2.5 or less. In addition, it is possible to separate palladium from other precious metals by performing reverse extraction using a second acidic solution having a lower pH than the original acidic solution.
机译:本发明以早期且高效的方式从含有贵金属的酸性溶液中提取贵金属。提供了一种由以下通式表示的贵金属萃取剂。式中,R 1和R 2分别表示相同的烷基或不同的烷基,R 3表示氢原子或烷基,R 4表示氢原子或非氨基且与±碳键合的任意基。作为氨基酸。通式优选具有甘氨酸单元,组氨酸单元,赖氨酸单元,天冬氨酸单元或N-甲基甘氨酸单元。通过使用贵金属萃取剂对含有贵金属的酸性溶液进行溶剂萃取,可以一次从含有大量各种杂质的溶液中全部回收多种贵金属。在回收贵金属时,优选将pH设定为3.0以下,进一步优选将pH设定为2.5以下。另外,可以通过使用具有比原始酸性溶液低的pH的第二酸性溶液进行反萃取来从其他贵金属中分离钯。

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