首页> 外国专利> amino or phosphine functionalized block copolymers, selectively halogenated block, and precursor block, membrane or film, apparatus, electrodeionization assembly, and method for preparing the amino or phosphine functionalized block copolymer

amino or phosphine functionalized block copolymers, selectively halogenated block, and precursor block, membrane or film, apparatus, electrodeionization assembly, and method for preparing the amino or phosphine functionalized block copolymer

机译:氨基或膦官能化的嵌段共聚物,选择性卤化的嵌段和前体嵌段,膜或膜,设备,电去离子组件和制备氨基或膦官能化的嵌段共聚物的方法

摘要

1/1 summary “amino or phosphine functionalized block polymers, selectively halogenated block polymers, precursor block, membrane or film, apparatus, electrodeionization assembly, and method for preparing the copolymer Amino or phosphino-functionalized block dimer - Selectively functionalized amino and phosphine block copolymers and their preparation, for use as anion exchange membrane materials. selectively functionalized block copolymers have at least two end blocks each of which are substantially free of amino and phosphino functional groups and have at least one inner block d which on average comprises at least one unit of functionalized polymer in amino and phosphine of the formula (i) wherein z is nitrogen or 12 phosphorus; R is hydrogen or alkyl; r is hydrogen or tertiary alkyl; each independently is hydrogen or alkyl optionally 1 to b substituted with one - (a-nr) r; or two groups r together with the z to which they are attached form an optionally substituted ring; x is 1, 2 1 or 3; straight chain alkylene optionally substituted with one or more b methyl and / or ethyl groups; and r and r each independently is hydrogen or alkyl; or a corresponding anion salt.
机译:1/1摘要“氨基或膦官能化的嵌段聚合物,选择性卤化的嵌段聚合物,前体嵌段,膜或膜,装置,电去离子组件以及制备共聚物的方法”氨基或膦化官能化的嵌段二聚体-选择性官能化的氨基和膦化嵌段共聚物及其制备,用作阴离子交换膜材料。选择性官能化的嵌段共聚物具有至少两个末端嵌段,每个末端嵌段基本上不含氨基和膦基官能团,并且具有至少一个内部嵌段d,该内部嵌段d在式(i)的氨基和膦中平均包含至少一个官能化聚合物单元)其中z是氮或12个磷; R为氢或烷基; r是氢或叔烷基;各自独立地是氢或任选地被一个-(a-nr)r取代的1至b的烷基;或两个基团r与它们所连接的z一起形成一个可选取代的环; x是1、2 1或3;任选被一个或多个b甲基和/或乙基取代的直链亚烷基; r和r分别独立地是氢或烷基;或相应的阴离子盐。

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