DIRECT SYNTHESIS OF Cu-CHA THROUGH THE COMBINATION OF A CU AND TETRAETHYLAMM COMPLEX, AND APPLICATIONS IN CATALYSIS

摘要

The present invention relates to a process for the direct synthesis of a material with a CHA zeolite structure in the silicoaluminate form thereof containing copper atoms, which comprises at least the following steps: (i) Preparation of a mixture which contains at least one water source, one copper source, one polyamine, one source of Y tetravalent element, one source of X trivalent element, the tetraethylammonium cation as the only OSDA and one source of alkaline or alkaline earth (A) cations, and wherein the synthesis mixture has the following molar composition: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒYO 2 : a X 2 O 3 : b OSDA : c A : d H 2 O : e Cu : f polyamine (ii) Crystallization of the mixture obtained in (i) in a reactor; (iii) Recovery of the crystalline material obtained in (ii).