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Heteroatom-Containing Nano-Carbon Materials, Methods and Applications for Their Preparation, and Dehydrogenation Methods for Hydrocarbons

机译:含杂原子的纳米碳材料,其制备方法和应用以及碳氢化合物的脱氢方法

摘要

The present invention provides a heteroatom-containing nano-carbon material, and a method for producing and using the heteroatom-containing nano-carbon material, wherein the content of oxygen is 1-6 wt% The content is 0-2 wt%, the carbon content is 92-99 wt%; In XPS, the ratio of the oxygen content measured at the peak (s) in the range of 531.0-532.5 eV and the oxygen content measured at the peak (s) in the range of 532.6-533.5 eV is 0.2-0.8; The ratio of the carbon content measured in peak (s) in the range 288.6-288.8 eV to the carbon content measured in peak (s) in the range 286.0-286.2 eV in spectroscopy is 0.2-1; The ratio of nitrogen to total nitrogen content measured at peak (s) in the range of 398.5-400.1 eV is 0.7-1. The heteroatom-containing nano-carbon material exhibits good catalytic performance in the dehydrogenation of hydrocarbons and can significantly increase the conversion of the starting material and the selectivity of the target product.
机译:本发明提供了一种含杂原子的纳米碳材料,以及制备和使用该含杂原子的纳米碳材料的方法,其中氧的含量为1-6wt%,含量为0-2wt%,碳含量为92-99重量%;在XPS中,在531.0-532.5eV范围内的峰处测得的氧含量与在532.6-533.5eV范围内的峰处测得的氧含量之比为0.2-0.8。在光谱学中,在峰中测得的碳含量在288.6-288.8 eV范围内的碳含量与在峰内测量的碳含量在286.0-286.2 eV范围内的比率为0.2-1;在398.5-400.1 eV范围内的一个或多个峰值处测得的氮与总氮含量之比为0.7-1。含杂原子的纳米碳材料在烃的脱氢中表现出良好的催化性能,并且可以显着提高起始材料的转化率和目标产物的选择性。

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