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N-heterocyclic carbene complexes of platinum and palladium and their use

机译:铂和钯的N-杂环卡宾配合物及其用途

摘要

Chemical compounds of the general formulas (I) and (II), wherein X is F, Cl, Br, I, weakly coordinating anions or non-coordinating anions, n is a number from 1 to 4, inclusive, wherein R 1 is a compound of general formula (I) Formulas (IV), Z1 and Z2, are selected from -F, -Cl, -I, -Br, -NO2, -RA, -O-RA, -S-RA, -COO-RA, -OC (O ) -RA and -N (RA) 2, Z6, Z7 and Z8 are selected from N, C-Z1 and C-Z2, wherein at least one of the atoms represented by Z6, Z7, Z8 is N, and wherein RA is an H, is an alkyl group, a halogenated alkyl group or a compound represented by the general formulas (III) and (IV),
机译:通式(I)和(II)的化合物,其中X为F,Cl,Br,I,弱配位阴离子或非配位阴离子,n为1至4的数字,包括1和4,其中R 1为通式(I)的化合物通式(IV),Z 1和Z 2选自-F,-Cl,-I,-Br,-NO 2,-RA,-O-RA,-S-RA,-COO- RA,-OC(O)-RA和-N(RA)2,Z 6,Z 7和Z 8选自N,C-Z 1和C-Z 2,其中由Z 6,Z 7,Z 8表示的原子中的至少一个是N,其中RA是H,是烷基,卤代烷基或由通式(III)和(IV)表示的化合物,

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