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A process for the solid phases sulfation of poly (d - glucosamine - co - n - d - acetyl glucosamine) en

机译:聚(d-氨基葡萄糖-co-n-d-乙酰氨基葡糖胺)固相硫酸化的方法

摘要

A process for the solid phases sulfation of poly (d - glucosamine - co - n - d - acetyl glucosamine) s, in which, for the pretreatment– to poly (d - glucosamine - co - n - d - acetyl glucosamine) s as solid in the form of films, fibers, textile structures, semifinished products or scaffolds– a polar aprotic or protic solvent or a mixture of at least one polar aprotic or protic solvent and a weakly polar solvent– and / or an aqueous polybasic acid solution– and / or at least one cross-linking agent for the cross-linking of poly (d - glucosamine - co - n - d - acetyl deficiency amines– with retention of the solid phase of the poly (d - glucosamine - co - n - d - acetyl glucosamine) e are added, and– subsequently the solids of the aqueous polybasic acid solution or the cross-linking agent is separated off, and– subsequently to the pretreated poly (d - glucosamine - co - n - d - acetyl glucosamine) s a solvent or solvent mixture and be added at least one sulfatierungsagens.
机译:聚(d-氨基葡萄糖-co-n-d-乙酰基氨基葡萄糖)固相硫酸化的方法,其中预处理为聚(d-氨基葡萄糖-co-n-d-乙酰基氨基葡萄糖)s呈膜,纤维,纺织结构,半成品或支架形式的固体–极性非质子或质子溶剂或至少一种极性非质子或质子溶剂与弱极性溶剂的混合物–和/或多元酸水溶液–和/或至少一种交联剂,用于聚(d-葡萄糖胺-共-n-d-乙酰缺乏胺-保留聚(d-葡萄糖胺-共-n-添加d-乙酰氨基葡糖),然后–分离多元酸水溶液或交联剂的固体,然后–预处理的聚(d-氨基葡糖-co-n-d-乙酰氨基葡糖) )溶剂或溶剂混合物,并至少加入一种硫磺酰脲。

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