Functionalized polyhydroxyalkanoate materials formed from an unsaturated polyhydroxyalkanoate material

摘要

A process of forming a functionalized polyhydroxyalkanoate (PHA) material includes performing an oxide elimination reaction (e.g., a selenoxide elimination reaction or a sulfoxide elimination reaction) on a saturated PHA material to form an unsaturated PHA material having a carbon-carbon double bond in a polymer backbone. The process also includes utilizing the unsaturated PHA material to form a functionalized PHA material. The functionalized PHA material has one or more cross-linkable functional groups (e.g., one or more thiol groups) bonded to a polymer backbone of the functionalized PHA material.