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Flavonoid derivative compounds and method for preparing same by depolymerization of condensed tannins

机译:类黄酮衍生物化合物及其缩合单宁解聚制备方法

摘要

A compound of general formula (I) in which R1, R2, R3 and R5, identical or different, each represent a hydrogen atom or a hydroxyl group, optionally protected by a protecting group. R4 represents a hydrogen atom or an —OR7 group, in which R7 represents a hydrogen atom, a protecting group or a gallate group. R6 represents a hydroxyl group, optionally protected by a protecting group. R′1, R′2, R′3 and R′4, identical or different, each represent a hydrogen atom or a substituent not comprising a mesomeric electron withdrawing group conjugated with the furan ring. A substituent from R′1, R′2, R′3 and R′4 representing the covalent bond with the pyran ring or one of the salts of same. A method for obtaining such a compound includes a step of depolymerization of condensed tannins in the presence of an acid by means of a nucleophile derived from furan.; embedded image
机译:通式(I)的化合物,其中R 1 ,R 2 ,R 3 和R 5 ,相同或不同,各自代表氢原子或羟基,任选地被保护基保护。 R 4 代表氢原子或-OR 7 基团,其中R 7 代表氢原子,保护基或没食子酸酯基。 R 6 表示一个羟基,可选地由保护基保护。 R' 1 ,R' 2 ,R' 3 和R' 4 相同或不同,分别表示氢原子或不包含与呋喃环共轭的中观吸电子基团的取代基。 R' 1 ,R' 2 ,R' 3 和R' 4 的取代基代表共价键与吡喃环或它们的盐之一。获得这种化合物的方法包括在酸存在下借助于衍生自呋喃的亲核试剂使缩合单宁解聚的步骤。 “嵌入式图像”

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